Memory properties of Fe-<i>x</i>Mn-6Si-9Cr-5Ni alloy by laser additive manufacturing with powder cored wire

ZHU Changshun; MAO Jizhou; WANG Hongyu; HUANG Jinlei; ZHU Jian

doi:10.12073/j.hjxb.20220819003

TRANSACTIONS OF THE CHINA WELDING INSTITUTION > 2023 > 44(7): 102-108. > DOI: 10.12073/j.hjxb.20220819003

ZHU Changshun, MAO Jizhou, WANG Hongyu, HUANG Jinlei, ZHU Jian. Memory properties of Fe-xMn-6Si-9Cr-5Ni alloy by laser additive manufacturing with powder cored wire[J]. TRANSACTIONS OF THE CHINA WELDING INSTITUTION, 2023, 44(7): 102-108. DOI: 10.12073/j.hjxb.20220819003

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Memory properties of Fe-xMn-6Si-9Cr-5Ni alloy by laser additive manufacturing with powder cored wire

Jiangsu University, Zhenjiang, 212013, China

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Received Date: August 18, 2022
Available Online: August 02, 2023

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Abstract

Abstract

In order to improve the performance of iron-based memory alloys and control the burning loss of elements during additive manufacturing, Fe-xMn-6Si-9Cr-5Ni (x = 14, 17 ,20) alloy with varying contents of Mn was prepared by laser directed energy deposition with powder cored wire. The shape recovery rate and microstructure of the alloy under different pre-deformation amounts were studied, and the memory performance optimization mechanism of the alloy was explored. The results showed that during powder cored wire laser additive manufacturing of Fe-xMn-6Si-9Cr-5Ni alloy, the burning rate of elements was only 25.6%, and low temperature martensites capable of improving the memory performance of the alloy were generted in the deposited alloy. When the mass fraction of Mn accounted for 17%, the shape recovery rate of the alloy reached 75% (with recoverable deformation at 3%) and 63% (with recoverable deformation at 3.78%) at a pre-deformation of 4% and 6%, respectively.
- iron-based memory alloy,
- laser additive manufacturing,
- powder core wire,
- low temperature ε martensite,
- memory performance

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References

Guenin G. Shape memory and pseudoelastic properties of Fe-Mn-Si and Ti-Ni based alloys[J]. Le Journal De Physique IV, 1997, 7(5): 467 − 476.

Sato A, Chishima E, Soma K, et al. Shape memory effect in γ transformation in Fe-30Mn-1Si alloy single crystals[J]. Acta Metallurgica, 1982, 30(6): 1177 − 1183. doi: 10.1016/0001-6160(82)90011-6

卢棋, 何国球, 陈淑娟, 等. 热机械训练过程中Fe-Mn-Si系形状记忆合金的组织演变[J]. 材料工程, 2015, 43(4): 8 − 12. doi: 10.11868/j.issn.1001-4381.2015.04.002

Lu Qi, He Guoqiu, Chen Shujuan, et al. Microstructure evolution of Fe-Mn-Si shape memory alloy during thermal mechanical training process[J]. Journal of Materials Engineering, 2015, 43(4): 8 − 12. doi: 10.11868/j.issn.1001-4381.2015.04.002

姚聪, 李瑞迪, 袁铁锤, 等. 激光送粉增材制造Fe-Mn-Si基形状记忆合金组织与性能[J]. 中南大学学报(自然科学版), 2020, 51(11): 3081 − 3087.

Yao Cong, Li Ruidi, Yuan Tiecui, et al. Microstructure and properties of Fe-Mn-Si based shape memory alloy by powder feeding laser additive manufacturing[J]. Journal of Central South University(Science and Technology), 2020, 51(11): 3081 − 3087.

奥妮, 何子昂, 吴圣川, 等. 激光增材制造AlSi10Mg合金的力学性能研究进展[J]. 焊接学报, 2022, 43(9): 1 − 19.

Ao Ni, He Ziang, Wu Shengchuan, et al. Recent progress on the mechanical properties of laser additive manufacturing AlSi10Mg alloy[J]. Transactions of the China Welding Institution, 2022, 43(9): 1 − 19.

Lee A Y, Jia A, Chua C K. Two-way 4D printing: A review on the reversibility of 3D-printed shape memory materials[J]. Engineering, 2017, 3(5): 663 − 674.

陈国庆, 树西, 张秉刚, 等. 国内外电子束熔丝沉积增材制造技术发展现状[J]. 焊接学报, 2018, 39(8): 123 − 128.

Chen Guoqing, Shu Xi, Zhang Binggang, et al. State-of-arts of electron beam freeform fabrication technology[J]. Transactions of the China Welding Institution, 2018, 39(8): 123 − 128.

Kim D, Ferretto I, Leinenbach C, et al. 3D and 4D printing of complex structures of Fe-Mn-Si-based shape memory alloy using laser powder bed fusion[J]. Advanced Materials Interfaces, 2022, 9(13): 1 − 11.

Ju H, Lin C X, Liu Z J, et al. Study of in-situ formation of Fe-Mn-Si shape memory alloy welding seam by laser welding with filler powder[J]. Optics & Laser Technology, 2018, 104: 65 − 72.

朱建, 王宏宇, 史东辉, 等. 增材制造记忆合金的元素烧损行为及其补损分析[J]. 焊接学报, 2022, 43(9): 50 − 55.

Zhu Jian, Wang Hongyu, Shi Donghui, et al. Element loss behavior and compensation of additive manufacturing memory alloy[J]. Transactions of the China Welding Institution, 2022, 43(9): 50 − 55.

赵磊. 基于微纳粉芯丝材的Fe-Mn-Si-Cr-Ni记忆合金增材制造工艺、组织和性能研究[D]. 镇江: 江苏大学, 2021.

Zhao Lei. Research on additive manufacturing process, microstructure and properties of Fe-Mn-Si-Cr-Ni memory alloy with micro-nano powder core wire[D]. Zhenjiang: Jiangsu University, 2021.

王宏宇, 黄金雷, 陈胜, 等. 基于Cu-Al-Fe合金的粉芯丝材增材制造理论及其温度场分析[J]. 焊接学报, 2023, 44(4): 111 − 119.

Wang Hongyu, Huang Jinlei, Chen Sheng, et al. Analysis of the theory and temperature field of additive manufacturing with powder core wire based on Cu-Al-Fe alloy[J]. Transactions of the China Welding Institution, 2023, 44(4): 111 − 119.

Wang H Y. Functional low-loss shape memory alloy micro-nano powder core wire material for laser additive manufacturing: WO, 2019223083[P]. 2019-11-28.

Li J C, Zhang Z, Jiang Q. Properties and application of Fe-6Si-14Mn-9Cr-5Ni shape memory alloy[J]. Materials Science and Technology:MST:A publication of the Institute of Metals, 2001, 17(3): 292 − 295.

孙广平. 铁锰硅铬镍形状记忆合金的组织性能及其制造管接头工艺性的研究[D]. 长春: 吉林大学, 2000.

Sun Guangping. Study on microstructure and properties of Fe-Mn-Si-Cr-Ni shape memory alloy and its manufacturability of pipe joint[D]. Changchun: Jilin University, 2000.

Ju H, Lin C X, Zhang J Q, et al. Research on residual stress inside Fe-Mn-Si shape memory alloy coating by laser cladding pr-ocessing[J]. Optoelectronics Letters, 2016, 12(5): 344 − 348. doi: 10.1007/s11801-016-6131-1

Zhang Q, Xu P, Zha G Q, et al. Numerical simulations of temperature and stress field of Fe-Mn-Si-Cr-Ni shape memory alloy coating synthesized by laser cladding[J]. Optik, 2021, 242: 167079. doi: 10.1016/j.ijleo.2021.167079

Xu P, Ju H, Lin C X, et al. In-situ synthesis of Fe-Mn-Si-Cr-Ni shape memory alloy functional coating by laser cladding[J]. Chinese Optics Letters, 2014, 12(4): 48 − 50.

Ferrett I, Kim D, Della Ventura N M, et al. Laser powder bed fusion of a Fe-Mn-Si shape memory alloy[J]. Additive Manufacturing, 2021, 46: 102071. doi: 10.1016/j.addma.2021.102071

Tian J Y, Xu P, Chen J H, et al. Microstructure and phase transformation behaviour of a Fe/Mn/Si/Cr/Ni alloy coating by laser cladding[J]. Optics and Lasers in Engineering, 2019, 122(9): 97 − 104.

Peng H B, Wen Y H, Du Y Y. Effect of manganese on microstructures and solidification modes of cast Fe-Mn-Si-Cr-Ni shape memory alloys[J]. Metallurgical and Materials Transactions B, 2013, 44(5): 1137 − 1143. doi: 10.1007/s11663-013-9880-2

Wu X C, Hsu T Y, Xu Z Y. Effect of the Neel temperature, T_N, on martensitic transformation in Fe-Mn-Si-based shape memory alloys[J]. Materials Characterization, 2000, 45(2): 137 − 142.

Li J C, Zhao M. Alloy design of Fe-Mn-Si-Cr-Ni shape memor-y alloys related to stacking-fault energy[J]. Metallurgical and Mat-erials Transactions A, 2000, 31(3): 581 − 584.

Zhao C. Relationships between martensite transformation temperatures and compositions in Fe-Mn-Si-based shape memory alloys[J]. Proceedings of the Institution of Mechanical Engineers, Part L: Journal of Materials: Design and Application, 2000, 214(3): 173 − 176. doi: 10.1243/0954405001517568

Verbeken K, Van Caenegem N, Verhaege M. Quantification of the amount of martensite in a Fe-Mn-Si-Cr-Ni shape memory alloy by means of electron backscatter diffraction[J]. Materials Science & Engineering: A, 2008, 481: 471 − 475.

Koyama M, Sawaguchi T, Tsuzaki K. Si content dependence on shape memory and tensile properties in Fe-Mn-Si-C alloys[J]. Materials Science & Engineering: A, 2011, 528(6): 2882 − 2888.

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Memory properties of Fe-xMn-6Si-9Cr-5Ni alloy by laser additive manufacturing with powder cored wire