Advanced Search
LIU Shuying, ZHANG Dongdong, LIU Yazhou, SUN Yanyan. Analysis of growth behavior of intermetallic compound in diffusion bonding of Ti alloy/Cu/stainless steel[J]. TRANSACTIONS OF THE CHINA WELDING INSTITUTION, 2019, 40(9): 133-138. DOI: 10.12073/j.hjxb.2019400249
Citation: LIU Shuying, ZHANG Dongdong, LIU Yazhou, SUN Yanyan. Analysis of growth behavior of intermetallic compound in diffusion bonding of Ti alloy/Cu/stainless steel[J]. TRANSACTIONS OF THE CHINA WELDING INSTITUTION, 2019, 40(9): 133-138. DOI: 10.12073/j.hjxb.2019400249
shu

Analysis of growth behavior of intermetallic compound in diffusion bonding of Ti alloy/Cu/stainless steel

  • 1.

    Henan University of Science and Technology, Luoyang 471023, China;Collaborative Innovation Center of Nonferrous Metals, Luoyang 471023, China

  • 2.

    Dongfeng Precision Casting, Shiyan 442000, China

  • 3.

    Henan University of Science and Technology, Luoyang 471023, China

More Information
  • Received Date: November 09, 2018
    Graphical Abstract
    • Abstract
  • The mechanical properties, the generation types, the formation order and the growth thickness of the Ti-6Al-4V/Cu/304 vacuum diffusion welded joint were investigated and studied by means of tensile, SEM scanning, energy spectrum analysis, XRD test and thermo kinetic analysis. The results show that under the bonding pressure of 5 MPa, the tensile strength of the joint increases first and then decreases with the increase of the bonding temperature and time, and the maximum joint is 163 MPa at the bonding temperature of 1 223 K and the time of 3.6 ks, and the excessive temperature and time are unfavorable to the joint performance. With copper foil as the intermediate layer, intermetallic compounds are not formed at the Cu/304 interface. However, a multilevel transitional tissue consisting of solid solution, intermetallic compound TixCuy, TixCuy, ect. is formed between the titanium alloy/Cu interface. The evolution of the structure from titanium to stainless steel side is as follows Ti2Cu, TiCu, TiCu2, TiCu3, TiCu4, Ti2Fe, FeTi, and TiFe2 intermetallic compounds. The order of the generation of the reactant is the lowest priority of the value of the ΔG; The effect of TixCuy on the joints strength of the intermetallic compound is slightly stronger than that of TixCuy compound. The fracture is caused by the fracture of the Ti2Cu intermetallic compound in the zone Ⅱ of the titanium alloy side, which extends into the diffusion layer of intermetallic compounds at the boundary of the zone Ⅱ-Ⅲ and is brittle fracture. Therefore, improving the interface structure from the titanium alloy/Cu side is the main way to improve the joints strength. According to the empirical formula, the layer thickness of the intermetallic compound can be controlled by adjusting the temperature and time.
    • FullText(HTML)
    • References (12)
  • 刘德义,蔡建伟,任瑞铭.钛/铜中间层/钢扩散焊复合管界面组织与性能[J].焊接学报, 2013, 34(1):49-52 Liu Deyi, Cai Jianwei, Ren Ruiming. Interface structure and properties of Ti/Cu interlayer/steel diffusion welded composite pipe[J]. Transactions of the China Welding Institution, 2013, 34(1):49-52
    刘彦峰,邱云云,张美丽,等.基于铜中间层的钛合金与不锈钢的真空扩散焊研究[J].兵器材料科学与工程, 2017, 40(5):10-14 Liu Yanfeng, Qiu Yunyun, Zhang Meili, et al. Vacuum diffusion welding of titanium alloy and stainless steel with copper interlayer[J]. Transactions of the China Welding Institution, 2017, 40(5):10-14
    刘彦峰,白佳铭,张美丽,等. TC4钛合金/304不锈钢异种材料扩散焊研究[J].兵器材料科学与工程, 2017, 40(3):86-90 Liu Yanfeng, Bai Jiaming, Zhang Meili, et al. Diffusion bonding of TC4 titanium alloy and 304 stainless steel[J]. Ordnance Material Science and Engineering, 2017, 40(3):86-90
    Deng Yongqiang, Sheng Guangmin, Yin Lijing. Impulse pressuring diffusion bonding of titanium to stainless steel using a copper interlayer[J]. Rare Metal Materials and Engineering, 2015, 44(5):1041-1045.
    冯吉才,李卓然,何鹏,等. TiAl/40Cr扩散连接接头的界面结构及相成长[J].中国有色金属学报, 2003, 13(1):162-165 Feng Jicai, Li Zhuoran, He Peng, et al. Interface structure and phase growth of TiAl/40Cr diffusion bonding joints[J]. Transactions of Nonferrous Metals Society of China, 2003, 13(1):162-165
    刘树英,张贵锋,刘广宝,等.钛合金与GCrl5扩散连接界面组织特征与性能[J].焊接学报, 2010, 31(9):69-72 Liu Shuying, Zhang Guifeng, Liu Guangbao, et al. Microstructure characteristic and performance of the bonding interface between the titanium alloy/copper/CCr15[J]. Transactions of the China Welding Institution, 2010, 31(9):69-72
    周媛,熊华平,陈波,等.以铜和Cu-Ti作为中间层的TiA1/GH353扩散焊[J].焊接学报, 2012, 33(2):17-20 Zhou Yuan, Xiong Huaping, Chen Bo, et al. TiA1/GH353 diffusion bonding with copper and Cu-Ti as interlayer[J]. Transactions of the China Welding Institution, 2012, 33(2):17-20
    Liu Shuying, Xu Kuan, Liu Guangbao, et al. The evolution characteristics and numerical analysis of diffusion bonding interface structure of titanium alloy/Cu/stainless steel[J]. Reviews on Advanced Materials Science, 2013, 33(3):224-231.
    郝士明,蒋敏,李洪晓.材料热力学(第二版)[M].北京:化学工业出版社, 2016 Hao Shiming, Jiang Min, Li Hongxiao. Thermodynamics of Materials[M]. Beijing:Chemical industry press, 2016
    韩丽青,王自东,龙斌,等.钛/不锈钢焊接界面金属间化合物的生成动力学[J].材料热处理学报, 2011, 32(2):61-64 Han Liqing, Wang Zidong, Long Bin et al. Kinetics of intermetallic compound formation on titanium/stainless steel bonding interface[J]. Transactions of Material Heat Treatment, 2011, 32(2):61-64
    赵玉谦,方世杰,赵宇光,等.(Ti, Fe)-Al-C体系钢铁基复合材料的热力学计算与分析[J].吉林大学学报(工学版), 2005, 35(4):343-347 Zhao Yuqian, Fang Shijie, Zhao Yuguang, et al. Thermodynamic calculation and analysis of steel matrix composites in (Ti, Fe)-Al-C system[J]. Transactions of Jilin University (Engineering Edition), 2005, 35(4):343-347
    Japanese Metallic Society. Metallic data book. the fourth revision edition.[M]. Tokyo:Maruzen Co., Ltd., 2004.
    • Related Articles

  • Related Articles

    [1]WU Chengfu, LI Xinyi, CHEN Hongsheng, LI Jian, NIE Huihui, WANG Wenxian. Interface connection mechanism and mechanical properties of WCp titanium matrix composites fabricated by laser additive[J]. TRANSACTIONS OF THE CHINA WELDING INSTITUTION, 2023, 44(3): 44-53. DOI: 10.12073/j.hjxb.20220425003
    [2]YANG Linmei, MU Guowan. Size distribution and growth mechanism of interfacial intermetallic compounds in Sn3.0Ag0.5Cu/Cu reflow solder joints[J]. TRANSACTIONS OF THE CHINA WELDING INSTITUTION, 2022, 43(4): 61-67. DOI: 10.12073/j.hjxb.20210915001
    [3]HUANG Junlan, LONG Weimin, ZHONG Sujuan, GENG Jinfeng, DING Tianran, QIN Jian. Effect mechanism of Ni-P coating on the structure and properties of Cu/Al joints[J]. TRANSACTIONS OF THE CHINA WELDING INSTITUTION, 2021, 42(5): 51-56, 70. DOI: 10.12073/j.hjxb.20201127001
    [4]ZHANG Bojun, YU Huajin, JING Hongyang, XU Lianyong, ZHAO Lei. Study on creep properties of deposited weld metal in nuclear class 316H pipe[J]. TRANSACTIONS OF THE CHINA WELDING INSTITUTION, 2019, 40(12): 97-101. DOI: 10.12073/j.hjxb.2019400320
    [5]SHEN Zhongbao, QIU Ranfeng, SHI Hongxin, MA Hengbo. Growth mechanism of intermetallic compounds at the solid-state joining interface of aluminum/steel[J]. TRANSACTIONS OF THE CHINA WELDING INSTITUTION, 2019, 40(6): 58-63. DOI: 10.12073/j.hjxb.2019400155
    [6]CUI Qinglong. Microstructure and mechanical properties of TIG welded-brazed joint of pre-coating titanium and aluminum alloy[J]. TRANSACTIONS OF THE CHINA WELDING INSTITUTION, 2016, 37(10): 125-128.
    [7]ZHANG Huiwen, CUI Wei, YAN Jiuchun. Interface microstructure and strengthening mechanism of Cu/Al dissimilar metal joint by ultrasonic-assisted soldering[J]. TRANSACTIONS OF THE CHINA WELDING INSTITUTION, 2015, 36(1): 101-104.
    [8]XU Xiaolong, LI Zhuoran, LIU Ruihua, WANG Zhengzheng. Microstructure and mechanical properties of ZrB2-SiC ceramic composite brazed joint[J]. TRANSACTIONS OF THE CHINA WELDING INSTITUTION, 2014, 35(1): 59-62.
    [9]HE Peng, FENG Ji-cai, QIAN Yi-yu, ZHANG Jiu-hai. Forming Mechanism of interface intermetallic Compounds for Difusion Bonding[J]. TRANSACTIONS OF THE CHINA WELDING INSTITUTION, 2001, (1): 53-55.
    [10]HE Peng, ZHANG Jiu-hai, FENG Ji-cai, QIAN Yi-yu. Numeric Simulation for Interface Intermetallic Compounds of Phase Transformation Diffusion Bonding[J]. TRANSACTIONS OF THE CHINA WELDING INSTITUTION, 2000, (3): 75-78.

  • Cited by

    Periodical cited type(7)

    1. 孙清洁，张清华，赵永庆，郭佳威，李天佑，班华康，侯少军. 核电厂定位销局部干法水下TIG焊接工艺. 焊接学报. 2024(02): 7-12+129 . 本站查看
    2. 周政，张潇，段洪斌，郝庆军，张晓冬，张斌，王登星，张力，高晶. 乏燃料水池水下局部干法焊接系统与设备研究. 金属加工(热加工). 2024(11): 22-27 .
    3. 徐文彦，吴彪，王洪福，汪春民，李刚，王城坡. 药芯焊丝组分及合金化调控研究现状及进展. 焊接技术. 2024(11): 8-16 .
    4. 周国丰，张清华，张红，孙清洁，王晓磊. 核电厂水下TIG焊炬设计及焊接工艺研究. 电焊机. 2023(11): 16-22 .
    5. 周超，李海新，杨振林，姜风春，王琪晨，张文杰. 水下湿法焊接接头质量控制技术研究现状. 焊接. 2021(06): 34-39+60+63 .
    6. 叶建雄，彭星玲，李兵. 水下湿法焊接研究进展. 电焊机. 2020(09): 111-117 .
    7. 朱征宇，张强勇，李晓泉，赵先锐，陈勇. 水下局部干法焊接技术的发展. 南京工程学院学报(自然科学版). 2019(04): 57-61 .

    Other cited types(13)

Catalog

    Get Citation
    PDF
    XML
    Article views (409) PDF downloads (151) Cited by(20)
    Turn off MathJax
    Article Contents
    Abstract
    References
    Related Articles

    Website Copyright © Editorial Office of Transactions of the China Welding Institution, Welding Journals Publishing HouseTel：0451-86323218Address：No. 2077, Chuangxin Road, Songbei District, Harbin

    Supported by: Beijing Renhe Information Technology Co. Ltd    Baidu Analytics

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return