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WANG Yongdong, GONG Shulin, CHANG Mengyang, WANG Jinyu, REN yuanda, JING zonghao. Effect of Nb components on the microstructure and mechanical properties of high-entropy alloy coatings[J]. TRANSACTIONS OF THE CHINA WELDING INSTITUTION, 2024, 45(3): 107-113. DOI: 10.12073/j.hjxb.20230329001
Citation: WANG Yongdong, GONG Shulin, CHANG Mengyang, WANG Jinyu, REN yuanda, JING zonghao. Effect of Nb components on the microstructure and mechanical properties of high-entropy alloy coatings[J]. TRANSACTIONS OF THE CHINA WELDING INSTITUTION, 2024, 45(3): 107-113. DOI: 10.12073/j.hjxb.20230329001

Effect of Nb components on the microstructure and mechanical properties of high-entropy alloy coatings

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  • Received Date: March 28, 2023
  • Available Online: December 19, 2023
  • CoCrFeNiTi0.8Nby (y = 0.25, 0.5, 0.75, 1.0) coatings were prepared on the surface of Q235 steel using laser cladding. The phase structure and microstructure of the coatings were analyzed by optical microscope (OM), X-ray diffractometer (XRD), scanning electron microscope (SEM) and energy dispersive spectroscopy (EDS). The hardness and wear resistance of the coatings were tested by micro-Vickers hardness tester and friction wear tester. The results show that the microstructure shows a typical dendritic crystal structure, and the addition of Nb elements decreases the size of the grains; by increasing the content of Nb elements, the crystal structure of the high-entropy alloy coatings consists of BCC phases, a small amount of FCC phases, and Fe2(Ti, Nb)-type Laves phases; the microhardness of the coatings is improved by the combined effect of fine-grained reinforcement, solid solution strengthening, and the strengthening of the second phase; The presence of the intermediate phase can hinder the plough cutting process to a certain extent, which improves the wear resistance of the coating; CoCrFeNiTi0.8Nb0.75 coating has the best hardness and wear resistance, the hardness of 710 HV, about 4 times that of the substrate, and the coating has the smallest amount of abrasion, and the abrasion marks are relatively flat.

  • [1]
    齐艳飞, 任喜强, 周景一, 等. 高熵合金涂层制备工艺的研究现状[J]. 稀有金属材料与工程, 2022, 51(2): 735 − 742.

    Qi Yanfei, Ren Xiqiang, Zhou Jingyi, et al. Research status of preparation technology of high entropy alloy coating[J]. Rare Metal Materials and Engineering, 2022, 51(2): 735 − 742.
    [2]
    王永东, 宫书林, 汤明日, 等. 激光熔覆工艺对高熵合金组织与性能影响[J]. 焊接学报, 2023, 44(8): 116 − 122. doi: 10.12073/j.hjxb.20220928001

    Wang Yongdong, Gong Shulin, Tang Mingri, et al. Effect of laser cladding process on the microstructure and properties of high entropy alloys[J]. Transactions of the China Welding Institution, 2023, 44(8): 116 − 122. doi: 10.12073/j.hjxb.20220928001
    [3]
    Liu A, Wang C. Progress in weldability research of high entropy alloys[J]. China Welding, 2023, 32(1): 53 − 62.
    [4]
    焦文娜, 卢一平, 曹志强, 等. 共晶高熵合金的研究进展及展望[J]. 特种铸造及有色合金, 2022, 42(3): 265 − 274. doi: 10.15980/j.tzzz.2022.03.001

    Jiao Wenna, Lu Yiping, Cao Zhiqiang, et al. Progress and prospect of eutectic high entropy alloys[J]. Special Casting & Nonferrous Alloys, 2022, 42(3): 265 − 274. doi: 10.15980/j.tzzz.2022.03.001
    [5]
    董天顺, 刘琦, 李艳姣, 等. 高熵合金涂层的研究现状及展望[J]. 材料保护, 2020, 53(7): 137 − 141. doi: 10.16577/j.cnki.42-1215/tb.2020.07.023

    Dong Tianshun, Liu Qi, Li Yanjiao, et al. Research status and prospect of high entropy alloy coatings[J]. Materials Protection, 2020, 53(7): 137 − 141. doi: 10.16577/j.cnki.42-1215/tb.2020.07.023
    [6]
    刘昊, 高强, 郜文鹏, 等. 激光熔覆CoCrFeNiNbx高熵合金涂层的高温摩擦磨损性能[J]. 摩擦学学报, 2022, 42(5): 966 − 977.

    Liu Hao, Gao Qiang, Gao Wenpeng, et al. High temperature tribological properties of CoCrFeNiNbx high-entropy alloy coatings by laser cladding[J]. Tribology, 2022, 42(5): 966 − 977.
    [7]
    王成, 李先芬, 刘昊, 等. 激光熔覆Co1.5CrFeNi1.5Ti0.75Nb x高熵合金的组织和性能研究[J]. 精密成形工程, 2021, 13(2): 81 − 86. doi: 10.3969/j.issn.1674-6457.2021.02.013

    Wang Cheng, Li Xianfen, Liu Hao, et al. Microstructure and properties of laser cladding Co1.5CrFeNi1.5Ti0.75Nbx high-entropy alloy[J]. Journal of Netshape Forming Engineering, 2021, 13(2): 81 − 86. doi: 10.3969/j.issn.1674-6457.2021.02.013
    [8]
    贾华, 高明, 刘政军. Ti和Nb对铁基堆焊合金组织性能的影响[J]. 焊接学报, 2023, 44(3): 87 − 91. doi: 10.12073/j.hjxb.20220412001

    Jia Hua, Gao Ming, Liu Zhengjun, et al. Effect of Ti and Nb on microstructure and properties of Fe based surfacing alloy[J]. Transactions of the China Welding Institution, 2023, 44(3): 87 − 91. doi: 10.12073/j.hjxb.20220412001
    [9]
    姜明明, 孙树峰, 王津, 等. 激光熔覆制备高熵合金涂层耐磨性研究进展[J]. 材料工程, 2022, 50(3): 18 − 32. doi: 10.11868/j.issn.1001-4381.2021.000605

    Jiang Mingming, Sun Shufeng, Wang Jin, et al. Research progress in wear resistance of high entropy alloy coatings prepared by laser cladding[J]. Journal of Materials Engineering, 2022, 50(3): 18 − 32. doi: 10.11868/j.issn.1001-4381.2021.000605
    [10]
    Xiang K, Chen L, Chai L, et al. Microstructural characteristics and properties of CoCrFeNiNb x high-entropy alloy coatings on pure titanium substrate by pulsed laser cladding[J]. Applied Surface Science, 2020, 517: 146214. doi: 10.1016/j.apsusc.2020.146214
    [11]
    Cheng J B, Liang X B, Xu B S. Effect of Nb addition on the structure and mechanical behaviors of CoCrCuFeNi high-entropy alloy coatings[J]. Surface and Coatings Technology, 2014, 240: 184 − 190. doi: 10.1016/j.surfcoat.2013.12.053
    [12]
    Wen X, Cui X, Jin G, et al. In-situ synthesis of nano-lamellar Ni1.5CrCoFe0.5Mo0.1Nb x eutectic high-entropy alloy coatings by laser cladding: Alloy design and microstructure evolution[J]. Surface & Coatings Technology, 2021, 405: 126728.
    [13]
    李坤. 添加C、Ti对CoFeNiMn高熵合金微观组织与力学性能影响的研究[D]. 西安: 西安工业大学, 2021.

    Li Kun. Effect of C and Ti on microstructure and mechanical properties of coFeNiMn high entropy alloys[D]. Xi'an: Xi'an Technological University, 2021.
    [14]
    张婷, 李双明, 李克伟, 等. 合金化元素Ti对Laves相Cr2Nb力学性能及耐蚀性的影响[J]. 稀有金属材料与工程, 2015, 44(3): 697 − 702.

    Zhang Ting, Li Shuangming, Li Kewei, et al. Effects of Ti addition on the mechanical properties and corrosion resistance of the Cr2Nb Laves phase[J]. Rare Metal Materials and Engineering, 2015, 44(3): 697 − 702.
    [15]
    苏允海, 梁学伟, 邓越, 等. FeAlCuCrNiNbx系高熵合金堆焊层的组织及性能分析[J]. 焊接学报, 2020, 41(4): 38 − 43. doi: 10.12073/j.hjxb.20191015001

    Su Yunhai, Liang Xuewei, Deng Yue, et al. Microstructure and property analysis of FeAlCuCrNiNbx high-entropy alloy surfacing layer[J]. Transactions of the China Welding Institution, 2020, 41(4): 38 − 43. doi: 10.12073/j.hjxb.20191015001
    [16]
    尚晓娟, 刘其斌, 郭亚雄, 等. Nb对激光熔覆MoFeCrTiWAlNbx高熔点高熵合金组织与性能的影响[J]. 功能材料, 2017, 48(12): 12214 − 12220.

    Shang Xiaojuan, Liu Qibin, GuoYaxiong, et al. Effect of Nb on microstructure and properties of laser cladding MoFeCrTiWAlNbx high-melting-point high-entropy alloy[J]. Journal of Functional Materials, 2017, 48(12): 12214 − 12220.
    [17]
    Zhang Ri, Gu X, Gong H, et al. Effect of Nb content on microstructure and properties of FeCoNi2CrMnV0.5Nbx high-entropy alloy coatings by laser cladding[J]. Journal of Materials Research and Technology, 2022, 21: 3357 − 3370. doi: 10.1016/j.jmrt.2022.10.144
    [18]
    Zhang Y, Han T, Xiao M, et al. Effect of Nb content on microstructure and properties of laser cladding FeNiCoCrTi0.5Nbx high-entropy alloy coating[J]. Optik-International Journal for Light & Electron Optics, 2019, 198: 163316.
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