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Ti3Al基合金TLP扩散连接界面的组织演变

Microstructure evolution of TLP bonding interface for Ti3Al based alloy

  • 摘要: 以Ti-37.5Zr-15Cu-10Ni(质量分数,%)非晶箔带为中间层,研究了TLP扩散连接Ti-23Al-17Nb(质量分数,%)合金的界面组织演变过程.结果表明,Ti元素和Nb元素向中间层扩散而Ni,Cu和Zr元素向母材扩散驱动了界面组织演变;在扩散初始阶段即930℃,保温5 min时,界面已形成冶金结合;随保温时间延长至15 min,界面析出条形TiNi3(Cu,Zr)化合物,其随保温时间延长更加细小呈弥散分布;直至保温时间延长至120~200 min,界面组织转变为均一、粗大的针状魏氏组织.保温时间是影响TiNi3(Cu,Zr)化合物析出形态和分布的主要因素,控制保温时间可有效改变界面化合物状态,该方法是优化此类界面组织以提高接头强度的有效途径.

     

    Abstract: With Ti-37.5Zr-15Cu-10Ni (%) amorphous foil as the brazing filler metal,the microstructure evolution of the TLP(Transient liquid phase) diffusion bonding interface for Ti3Al-based alloys was studied. The Ti and Nb elements diffuse into the brazing filler and the Ni,Cu,Zr elements diffuse into the matrix to drive the interface evolution. At 930℃ the metallurgical bonding is achieved after holding time of 5 min. The TiNi3 (Cu,Zr) compound in the shape of strip is precipitated after holding time of 15 min. This compound will get refined and dispersed with the holding time being longer. When the holding time lasts until to 120-200 min,the interface microstructure evolved to the coarse and homogeneous Widmanstaten structure. Since the compound character is affected by the holding time,it can be an effective method to control the microstructure and strengthen the interface by controlling the holding time.

     

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