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Ti6Al4V合金表面激光熔覆XSiC/NiCrAl复合涂层组织和性能

Microstructure and properties of XSiC/NiCrAl composite coatings prepared by laser cladding on Ti6Al4V alloy surface

  • 摘要: 基于钛合金表面耐磨损的防护需求,采用激光熔覆技术在Ti6Al4V表面制备了不同SiC含量的SiC/NiCrAl复合防护涂层. 通过分析相、表面形貌、元素分布、摩擦性能曲线和电化学性能曲线,表征复合涂层的显微组织、显微硬度、摩擦学性能以及耐腐蚀性能. 结果表明,涂层无明显的气孔和裂纹的等缺陷,制备的XSiC/NiCrAl复合涂层主要由Cr2Si相、TiC相、(Ti,Al)-rich FCC2相、(Ni,Ti,Al)-rich BCC3相和(Ni,Al,Si)-rich BCC2相组成. 随着SiC含量增加,涂层中原位形成了TiC和(Ni,Al,Si)-rich HCP1新相,且表面显微硬度和耐磨性也随之增加,而耐蚀性能逐渐减低. 其中NiCrAl-6SiC涂层的平均显微硬度最高和磨损失重最小(919.4 HV0.3,0.6 mg),而NiCrAl-4SiC的平均显微硬度和磨损失重损失(895.6 HV0.3,0.8 mg)与Ni60-6SiC涂层相近,耐蚀性能更优异,NiCrAl-4SiC涂层的综合性能更优异.

     

    Abstract: To meet the requirement of wear-resistant protection for titanium alloy surfaces, SiC/NiCrAl composite protective coatings with different SiC contents were prepared on the Ti6Al4V surface by laser cladding technology. The microstructure, microhardness, tribological properties, and corrosion resistance of the composite coatings were characterized by analyzing phases, surface morphology, element distribution, friction performance curves, and electrochemical performance curves. The results indicate that the coatings have no obvious defects such as pores and cracks. The prepared XSiC/NiCrAl composite coatings are mainly composed of Cr2Si phase, TiC phase, (Ti, Al)-rich FCC2 phase, (Ni, Ti, Al)-rich BCC3 phase, and (Ni, Al, Si)-rich BCC2 phase. With the increase of SiC content, new phases of TiC and (Ni, Al, Si)-rich HCP1 are formed in situ in the coatings, and the surface microhardness and wear resistance increase accordingly, while the corrosion resistance gradually decreases. Among them, the NiCrAl-6SiC coating has the highest average microhardness and the smallest wear weight loss (919.4 HV0.3, 0.6 mg). The average microhardness and wear weight loss of the NiCrAl-4SiC coating (895.6 HV0.3, 0.8 mg) are close to those of the Ni60-6SiC coating, and its corrosion resistance is more excellent; therefore, the NiCrAl-4SiC coating exhibits a superior comprehensive performance.

     

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