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高温服役的陶瓷−可伐合金钎焊技术

Brazing technology of ceramic-Kovar alloy for high-temperature service

  • 摘要: 针对高温工况下陶瓷与可伐合金的钎焊难题,采用耐高温性能更优的金−镍钎料(替代传统研究中使用的银−铜-钛钎料),对氧化铝陶瓷与可伐合金进行钎焊连接. 此外,还探究了不同焊接温度对氧化铝陶瓷−可伐合金钎焊接头抗剪强度的影响,并分析了钎焊温度、接头显微组织与抗剪断裂位置之间的关联性. 结果表明,当焊接温度为 1 000 ℃、保温时间为 10 min时,钎焊接头的抗剪强度达到最高,可达 124.8 MPa;钎焊接头在 450 ℃时的抗剪强度降至室温强度的 38.5%,在 550 ℃时,其抗剪强度仍保持在 37 MPa 以上. 研究成果为陶瓷−金属连接技术在高温环境下的工程应用,提供了重要的理论依据与工艺参数参考.

     

    Abstract: In view of the brazing challenge of ceramics and Kovar alloys under high-temperature service conditions, gold-nickel brazing filler metal with superior high-temperature resistance, which replaced the silver-copper-titanium brazing filler metal used in traditional studies, was adopted for the brazing of alumina ceramics and Kovar alloys. In addition, the effects of different brazing temperatures on the shear strength of alumina ceramic-Kovar alloy brazed joints were investigated, and the correlation among brazing temperature, joint microstructure, and shear fracture position was analyzed. The results show that when the brazing temperature is 1 000 ℃, and the holding time is 10 min, the shear strength of the brazed joint reaches a maximum of 124.8 MPa. At 450 ℃, the shear strength of the joint decreases to 38.5% of its room-temperature strength, and at 550 ℃, its shear strength remains above 35 MPa, which is approximately 21.5% lower than that at 450 ℃. The research results provided an important theoretical basis and process parameter reference for the engineering application of ceramic-metal joining technology in high-temperature environments.

     

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