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SUS410/Hastelloy X接头钎焊工艺及高温性能

Brazing process and high-temperature performance of SUS410/Hastelloy X joint

  • 摘要: 采用BNi-2粘带钎料实现了SUS410和Hastelloy X异种材料的真空钎焊连接,利用扫描电子显微镜( energy dispersive spectrometer,SEM)与能谱仪(energy dispersive spectrometer,EDS)分析了钎焊接头界面微观组织,研究了钎焊时间对接头界面组织及力学性能的影响规律,为了评价接头高温服役性能,研究了高温(620 ℃)时效对接头界面组织及高温力学性能的影响规律. 结果表明,钎焊接头的典型界面组织为SUS410/ α-Fe + (Fe, Cr)-B/ Ni(s, s) + Cr-B/γ-phase + (Ni, Cr, Fe)-B + (Cr-B, Mo-B)/ Hastelloy X. 随着钎焊时间延长,接头抗剪强度先增大后减小,当钎焊温度为1 100 ℃,保温时间为10 min时,接头获得最大抗剪强度为216.8 MPa,断裂形式为韧性断裂;经过620 ℃时效后,接头扩散区的面积均显著增大,并随着时间的延长进一步增大;时效后接头扩散区内晶界处的硼化物数量分布更为均匀,在晶界处的聚集程度降低;随着时效时间的延长,高温(620 ℃)抗剪强度逐渐收敛在138.2 ~ 145.9 MPa,达到室温抗剪强度的63.7% ~ 67.3%.

     

    Abstract: The vacuum brazing of SUS410 stainless steel to Hastelloy X dissimilar materials was successfully executed utilizing BNi-2 adhesive tape as the brazing alloy. The microstructure of the brazed joint interface was analyzed using an energy dispersive spectrometer (SEM) and an energy dispersive spectrometer (EDS). The influence of brazing duration on the interfacial microstructure and mechanical properties was investigated. In order to evaluate the high-temperature service performance of the joint, the influence of high-temperature (620 ℃) aging on the interface microstructure and high-temperature mechanical properties of the joint was studied. The results show that the typical interface structure of the brazed joint is SUS410/α-Fe+(Fe, Cr)-B/Ni(s, s)+Cr-B/γ-phase+(Ni, Cr, Fe)-B+(Cr-B, Mo-B)/Hastelloy X. As brazing continues, the shear strength of the joint first increases and then decreases. When the brazing temperature is 1 100 ℃, and the holding time is 10 minutes, the joint achieves the maximum shear strength of 216.8 MPa. The fracture is a ductile one. After aging at 620 ℃, the area of the diffusion zone at the joint has significantly increased, and this increase continues to grow over time. After the aging, the distribution of borides at the grain boundaries within the diffusion zone of the joint becomes more uniform, and the aggregation degree at the grain boundaries decreases. As aging continues, the shear strength at high temperature (620 ℃) gradually converges to 138.2–145.9 MPa, reaching 63.7%–67.3% of the shear strength at room temperature.

     

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