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超声辅助钎焊镀锌TC4/AZ31接头组织及性能

Microstructure and properties of ultrasonic-assisted brazing of galvanization TC4/AZ31 dissimilar alloy joints

  • 摘要: 为了实现TC4/AZ31在大气环境下的低温直连,采用超声辅助预镀对TC4进行表面改性,随后采用超声辅助钎焊方法实现改性后的TC4与AZ31连接,解决了Ti和Mg元素不互溶、不反应导致的无法直连的问题. 首先利用ABAQUS模拟了超声作用下TC4表面镀锌动态过程,得到最佳超声辅助预镀参数为变幅杆浸入50 mm,热浸温度500 ℃,振幅10 μm时,锌液池内TC4表面最大流速0.23 m/s,表面最大声压28.5 MPa;其次,对TC4进行超声辅助热浸镀锌,在其表面形成均匀(TiZn3,TiZn3 + TiZn16和η-Zn)镀层;最后,采用超声辅助钎焊连接TC4/AZ31,研究了钎焊温度、超声时间对异质接头微观形貌及性能的影响. 实现了镀锌TC4与AZ31在230 ℃的低温连接,钎缝由(TiZn3,TiZn3 + TiZn16和η-Zn)层、(β-Sn + η-Zn)层及Mg2Sn组成;随着超声时间延长,Mg2Sn厚度增加,钎缝整体宽度减小,接头抗剪强度由脆性Mg2Sn层的厚度及形态控制,超声5 s时,Mg2Sn厚度为6.7 μm,钛/镁异质接头抗剪强度达到47.7 MPa.

     

    Abstract: In order to realize the low temperature direct joining of TC4/AZ31 in the atmospheric environment, the surface modification of TC4 was carried out by ultrasonic assisted pre-plating, and then the ultrasonic assisted brazing method was used to realize the bonding between the modified TC4 and AZ31, which solved the problem that Ti and Mg elements could not be directly brazed due to their insolubility and non-reaction. Firstly, the dynamic process of zinc plating on TC4 surface under ultrasonic action was simulated by ABAQUS, and the optimal ultrasonic-assisted pre-plating parameters were obtained : when the hot-dip temperature was 500 ℃, the diameter of the sonotrode was 50 mm, and the amplitude was 10μm, the maximum flow rate of TC4 surface in the zinc bath was 0.23 m/s, and the average surface sound pressure was 13.1 MPa. Secondly, ultrasonic-assisted hot-dip galvanizing was performed on TC4 to form a uniform ( TiZn3, TiZn3 + TiZn16, η-Zn ) coating on its surface. Finally, ultrasonic-assisted brazing was used to join TC4/AZ31, and the effects of brazing temperature and ultrasonic time on the microstructure and properties of heterogeneous joints were studied. The low temperature joining of galvanized TC4 and AZ31 was realized at 230 ℃. The brazing seam was composed of ( TiZn3, TiZn3 + TiZn16, η-Zn ) layer, ( β-Sn + η-Zn ) layer and Mg2Sn. With the increase of ultrasonic time, the thickness of Mg2Sn increases, and the overall width of the brazing seam decreases. The shear strength of the joint is controlled by the thickness and morphology of the brittle Mg2Sn layer. When the ultrasonic time is 5 s, the thickness of Mg2Sn is 6.7 μm, and the average shear strength of the Ti/Mg dissimilar joint reaches 47.7 MPa.

     

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