高级检索

基于干式气溶胶喷印导电银线的烧结工艺研究

Research on sintering process of conductive silver wire based on dry aerosol jet printing

  • 摘要: 探究不同烧结方法及工艺参数对干式气溶胶喷印导电银线的显微组织与导电性能的影响. 利用自制喷印系统,以导电银线烧结前后横截面平均面积变化与烧结前的比为收缩率,电阻率变化与烧结前的比为电阻率变化率,分析基底加热对成形的影响,并分析和对比马弗炉烧结与激光烧结的作用效果. 试验表明,基底加热可减小导电银线的横截面面积与孔隙率,有效抑制飞溅. 在马弗炉加热温度为200 ℃的烧结条件下,在10 ~ 30 min 内收缩率从4.48%提高到 7.45%,电阻率变化率从74.17% 提高到92.48%,最小电阻率为17.79 μΩ∙cm;当激光烧结的激光功率为0.7 mW时,激光扫描速度为5 ~ 15 mm/min,收缩率从4.24%降低到 2.11%,电阻率变化率从86.74%降低到85.46%,最小电阻率为 24.82 μΩ∙cm. 能量的输入会促使纳米银颗粒团聚并建立连接,提升线条致密性;激光烧结凭借局部快速加热优势,避免了氧敏感金属广泛氧化及银线断裂脱落.

     

    Abstract: The effects of different sintering methods and process parameters on the microstructure and electrical conductivity of conductive silver wires produced by dry aerosol jet printing were investigated. By using a self-developed jet printing system, the area shrinkage rate was defined as the ratio of the change in the average cross-sectional area of the conductive silver wires before and after sintering to that before sintering, and the resistivity change rate was defined as the ratio of the change in resistivity to that before sintering. The forming effects of substrate heating and non-heating were analyzed, and the outcomes of Muffle furnace sintering and laser sintering were compared and analyzed. Experiments demonstrate that substrate heating reduces the cross-sectional area and porosity of conductive silver wires, effectively suppressing overspray. Under sintering conditions at 200 °C in a Muffle furnace, the shrinkage rate increases from 4.48% to 7.45% within 10 ~ 30 min, while the resistivity change rate rises from 74.17% to 92.48%. The minimum resistivity reaches 17.79 μΩ·cm. When the laser power for laser sintering is set to 0.7 mW, and the laser scanning speed is at 5~15 mm/min, the shrinkage rate decreases from 4.24% to 2.11%; the resistivity change rate decreases from 86.74% to 85.46%, and the minimum resistivity reaches 24.82 μΩ·cm. Energy input promotes the agglomeration and bonding of silver nanoparticles, enhancing line density. Laser sintering, leveraging its advantage of localized rapid heating, prevents extensive oxidation of oxygen-sensitive metals and silver wire breakage and detachment.

     

/

返回文章
返回