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C含量对等离子熔覆Al1.5CoCrFeNiNb0.2Cx高熵合金组织及性能的影响

Effect of C content on microstructure and mechanical properties of plasma claddingAl1.5CoCrFeNiNb0.2Cxhigh-entropy alloys

  • 摘要: 利用等离子熔覆技术在低碳钢表面制备了不同C含量的Al1.5CoCrFeNiNb0.2Cx(x = 0, 0.01, 0.02, 0.05, 0.2,摩尔比)高熵合金熔覆层,采用采用X射线衍射仪 (X-ray diffraction,XRD),、扫描电镜(scanning electron microscope,SEM)、透射电镜 (transmission electron microscopy,TEM)、硬度仪以及磨损试验机等手段,研究C含量对熔覆层微观组织以及力学性能的影响规律. 结果表明,x = 0、0.01时,Al1.5CoCrFeNiNb0.2Cx高熵合金的物相由BCC相以及少量富Nb的Laves相组成;x = 0.02 ~ 0.2时,能够原位合成NbC,且随着C含量的升高,NbC的析出量逐渐增加. x = 0、0.01时,高熵合金的微观组织为树枝晶结构,枝晶为BCC相,枝晶间为BCC相 + 富Nb的Laves相组成的共晶组织. x = 0.02 ~ 0.2时,树枝晶基体上析出原位合成NbC,并且随着C含量的升高,NbC的析出量和尺寸逐渐增大,其形貌由低含量下(x = 0.02、0.05)的颗粒状逐渐转变为高含量下(x = 0.2)的颗粒状以及十字状. TEM表明,高熵合金基体与NbC增强相之间的界面光滑纯净,没有任何缺陷以及其他污染物. 随着C含量由x = 0增加至x = 0.2,熔覆层硬度由560.1 HV增加至762.2 HV,磨损率由24.69 mg/min降低至4.70 mg/min.

     

    Abstract: : Al1.5CoCrFeNiNb0.2Cx(x = 0, 0.01, 0.02, 0.05, 0.2, molar ratio) high-entropy alloys with different C contents were prepared by plasma cladding on the surface of low-carbon steel. The effect of C content on the microstructure and mechanical properties of cladding layers was studied by using X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscopy (TEM), microhardness tester and wear testing machine. The results indicated that when x = 0 and 0.01, the Al1.5CoCrFeNiNb0.2Cx high-entropy alloys were composed of a BCC phase and a small amount of Nb-Laves phase. When x = 0.02-0.2, NbC phase could be synthesized in-situ. The alloys consist of a BCC phase, along with a small amount of NbC and Laves phase. Moreover, the precipitation amount of NbC gradually increased with the increase of C content. With the increase of C content, the NbC content increased gradually. When x = 0 and 0.01, the microstructure of high-entropy alloys was dendritic crystal. The dendrite was BCC phase and the interdendritic was eutectic texture consisted of BCC phase and Nb-Laves phase. When x = 0.02-0.2, in-situ NbC was precipitated on the dendritic matrix. With increasing C content, the content and size of NbC gradually increased, and its morphology was gradually transformed from granular at low C contents (x = 0.02, 0.05) to granular and cross-dendritic at high C content (x = 0.2). TEM showed that the interface between the high-entropy alloy matrix and the NbC reinforcement phase was smooth and clean, without any defects or impurities. As the C content rose from x = 0 to x = 0.2, the hardness increased from 560.1 HV to 762.2 HV, while the weight loss rate decreased from 24.69 mg/min to 4.70 mg/min.

     

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