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Al2O3陶瓷与多体系金属一体化钎焊结构优化与封接可靠性

Al2O3 ceramic and multi-system metal integrated brazing structure optimization and sealing reliability

  • 摘要: 通过有限元计算对0Cr18Ni9不锈钢壳体、Al2O3绝缘陶瓷和Kovar中心电极构成的电气连接器一体化钎焊结构进行优化,在此基础上采用Ag-5Cu-1Al-1.25Ti钎料在930 ℃/30 min的钎焊参数下实现该密封构件的一步封接,并对接头界面组织和服役可靠性进行研究. 结果表明,通过改进焊接位置和钎料添加形式,陶瓷基体的残余应力显著降低. 钎焊过程中,液态钎料中的活性Ti向陶瓷侧聚集并发生化学反应. Al2O3陶瓷侧形成连续的Ti3(Cu, Al)3O反应层,不锈钢一侧的反应产物主要为TiFe2和Fe-Cr金属间化合物,而Kovar母材向液态钎料溶解并与Ti反应形成Ti2Ni和TiFe2. 密封构件经历温冲循环后,泄漏率低于7.0 × 10−12 Pa·m3/s,证明了其在极端条件下的可靠性. 本研究结果可为极端温度变化条件服役电气连接器的设计提供仿真数据支撑和理论指导.

     

    Abstract: The integrated brazing structure of an electrical connector consisting of 0Cr18Ni9 stainless steel shell, Al2O3 insulating ceramic and Kovar central electrode was optimized by finite element calculations. On this basis, Ag-5Cu-1Al-1.25Ti brazing alloy was used to realize one-step sealing of the component at 930 ℃/30 min. The microstructure of the joints and the service reliability of the component were analyzed. The results indicate that the residual stress of the ceramic matrix can be significantly reduced by improving the welding position and brazing alloy addition form. During the brazing process, the active element Ti accumulated towards the ceramic side and reacted. Ti3(Cu, Al)3O reactive layer was formed on the Al2O3 ceramic side; the reaction products on the stainless steel side were TiFe2 and Fe-Cr intermetallic compounds; while the Kovar base material dissolves into the liquid brazing alloy and reactes with Ti to form Ti2Ni and TiFe2. The leakage rate of the composite component is less than 7.0 × 10−12 Pa·m3/s after the thermal cycles, verifying its reliability under extreme conditions. The research findings can provide simulation data support and theoretical guidance for the design of electrical connectors under extreme temperature change conditions.

     

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