Abstract:
The active metal brazed joints of Si
3N
4 and Cu were obtained by using Ag-Cu-In-Ti brazing filler at a brazing temperature of 780 °C. The interfacial microstructure of the joint and its formation mechanism were investigated, and the effect of holding time on the interfacial microstructure and mechanical properties of the joint was analyzed. The results have shown that during brazing, the Ti element reacts with Si
3N
4 to form a 170 nm-thick nanocrystalline TiN and a Ti
5Si
3 layer with a wavy profile. In the brazing seam, the residual Ti atoms after the reaction integrate with two brittle compounds, Cu
2InTi and Cu
4Ti. In addition, a very small amount of Cu
3Ti
2 and CuTi phases occurs. By regulating the reaction process at the Si
3N
4 ceramic-side interface, the holding time controls the morphology of the Ti
5Si
3 reaction products, as well as the content of brittle Cu
2InTi and Cu
4Ti compounds in the brazing seam, which determines the shear strength of the brazing joints. With the extension of the holding time, the interfacial reaction becomes more sufficient, and the amount of brittle intermetallic compounds in the brazing seam decreases. When the holding time is 20 min, the shear strength of the joints reaches the highest, with a value of 309 MPa. The fracture occurs at the interfacial reaction bilayer close to the Si
3N
4 ceramic, among which the Ti
5Si
3 is weaker.