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Al2O3陶瓷玻璃钎焊接头原位强化及机理

In-situ strengthening mechanism of glass brazing Al2O3 ceramics joints

  • 摘要: 针对Al2O3陶瓷可加工性差、复杂结构及大尺寸构件制备困难等问题,文中提出采用具有优异力学性能且与Al2O3陶瓷原位形成增强相的48.5%SiO2-48.5%B2O3-3%Na2O硼硅酸盐玻璃钎料钎焊连接Al2O3陶瓷. 结果表明,在钎焊连接过程中,Al2O3陶瓷向玻璃钎料内部扩散溶解,焊缝区域由SiO2-B2O3-Na2O玻璃转变为SiO2-B2O3-Al2O3-Na2O,Al2O3的融入强化了玻璃基体,同时在玻璃基体内部以及玻璃钎料与Al2O3陶瓷界面结合处均原位生成了大量弥散分布的硼酸铝晶须,形成了Al2O3陶瓷的硼酸铝晶须增强硼硅酸盐玻璃复合接头,晶须通过拔出效应、裂纹偏转、裂纹桥联、吸收效应等不仅进一步强化玻璃基体,对连接界面处更是起到了钉扎、缝合的作用,实现了Al2O3陶瓷高强度、高可靠连接. 当连接温度为1 250 ℃,保温时间为60 min时,接头剪切强度达到136 MPa.

     

    Abstract: In view of the problems of poor machinability, difficult preparation of complex structure and large-size components of Al2O3 ceramics, 48.5%SiO2-48.5%B2O3-3%Na2O borosilicate glass was used to obtain reliable bonding of Al2O3 ceramic which not only had excellent mechanical properties, but also can form an in-situ reinforced phase with Al2O3 ceramics. It was shown that during the brazing process, as Al2O3 ceramics diffusing and dissolving into the glass braze, SiO2-B2O3-Na2O glass transformed to SiO2-B2O3-Al2O3-Na2O glass in the seam. The integration of Al2O3 strengthened the glass matrix. Furthermore, a large number of dispersed aluminum borate whiskers were in-situ generated not only inside the glass matrix but also at the interface between glass braze and Al2O3 ceramics, forming the in-situ aluminum borate whiskers reinforced composite Al2O3/Al2O3 joints brazed by borosilicate glass. The whiskers not only further strengthened the glass matrix through pull-out effect, crack deflection, crack bridging, absorption effect, etc., but also played the role of nailing and suturing at the interface, realizing a high-strength and high-reliability connection of Al2O3 ceramics. When temperature is 1 250 ℃ and time is 60 min, the joint strength reached the highest value of 136 MPa.

     

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