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纳米铝颗粒增强Sn1.0Ag0.5Cu钎料性能及机理

Properties and mechanism of nano Al particles reinforced Sn1.0Ag0.5Cu solders

  • 摘要: 通过机械混合的方法,制备Sn1.0Ag0.5Cu-xAl复合钎料.采用DSC、STR-1000型微焊点强度测试仪及SEM,研究了纳米铝颗粒对低银Sn1.0Ag0.5Cu钎料组织与性能的影响.结果表明,微量纳米铝颗粒的添加对钎料的熔化温度影响较小,其熔点均在226.9~229.0℃之间.随着纳米Al元素含量的增加,钎料的润湿角逐渐减小,力学性能逐渐增加,当纳米Al元素的添加量为0.1%时,焊点的拉伸力达到最大,为7.1 N.此外,Sn1.0Ag0.5Cu-0.1Al钎料的内部组织得到显著细化,焊点界面金属间化合物的生长也得到明显抑制,主要归因于纳米颗粒对金属间化合物生长的吸附作用.

     

    Abstract: Sn1.0Ag0.5Cu-xAl composite solders were prepared by mechanically mixing method. The effect of nano Al particles on the microstructure and properties of Sn1.0Ag0.5Cu solder were investigated by differnetial scanning calorimetry, STR-1000 micro-joint strength tester and SEM. The results showed that adding nano Al particles does not cause a considerable change in the melting temperature. All samples ranged from 226.9 to 229℃. With the addition of nano Al particles, the wetting angle was decreased and mechanical property was increased. When the addition of nano Al particles was 0.1%, the pull force of solder joint reached the maximum, which was 7.1 N. In addition, the microstructure of Sn1.0Ag0.5Cu-0.1Al solder was significantly refined, and the thickness of interfacial intermetallic compounds (IMC) was effectively inhibited, which may attributed to the adsorption of nanoparticles.

     

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