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镍基合金激光熔覆-离子渗硫复合改性层组织性能

韩彬, 张蒙科, 崔岗, 王勇

韩彬, 张蒙科, 崔岗, 王勇. 镍基合金激光熔覆-离子渗硫复合改性层组织性能[J]. 焊接学报, 2016, 37(10): 1-4,96.
引用本文: 韩彬, 张蒙科, 崔岗, 王勇. 镍基合金激光熔覆-离子渗硫复合改性层组织性能[J]. 焊接学报, 2016, 37(10): 1-4,96.
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HAN Bin, ZHANG Mengke, CUI Gang, WANG Yong. Microstructure and properties of Ni based alloy composite coating by laser cladding-ion sulfurizing process[J]. TRANSACTIONS OF THE CHINA WELDING INSTITUTION, 2016, 37(10): 1-4,96.
Citation: HAN Bin, ZHANG Mengke, CUI Gang, WANG Yong. Microstructure and properties of Ni based alloy composite coating by laser cladding-ion sulfurizing process[J]. TRANSACTIONS OF THE CHINA WELDING INSTITUTION, 2016, 37(10): 1-4,96.
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镍基合金激光熔覆-离子渗硫复合改性层组织性能

  • 中国石油大学(华东)机电工程学院, 青岛 266580

基金项目: 国家自然科学基金资助项目（51179202）；国家高技术研究发展计划资助项目（863计划）（2012AA09A203）；清华大学摩擦学国家重点实验室开放基金资资助项目（SKLTKF13B04）；研究生创新基金资助项目（16CX06018A）

Microstructure and properties of Ni based alloy composite coating by laser cladding-ion sulfurizing process

  • College of Mechanical and Electronic Engineering, China University of Petroleum(Huadong), Qingdao 266580, China

摘要

    摘要
  • 摘要: 利用激光熔覆和离子渗硫技术在45钢表面制备复合改性层，采用SEM，EPMA，XRD等手段对比研究激光熔覆层和渗硫层的组织形貌、成分分布及相组成；并测试渗硫前后涂层的耐磨性和耐蚀性.结果表明，镍基合金涂层主要由γ-（Fe，Ni），Fe0.64Ni0.36，M23C6，WC，M7C3和Fe2B等物相组成，显微硬度达到740 HV0.2.渗硫后在激光熔覆层表面形成了以FeS为主的渗硫层，表面疏松多孔，由微纳米级的尖岛状颗粒堆砌而成.与熔覆层相比，复合改性层的摩擦系数和磨损量都显著降低，减摩和耐磨效果明显.渗硫后镍基合金激光熔覆层自腐蚀电位下降，腐蚀电流密度增大，耐蚀性略微降低.
    Abstract: The composite layer was produced on 45 steel substrate by laser cladding and low temperature ion sulfurizing process. The microstructure and phase composition of laser cladding layer and sulfurizing layer were studied by the means of SEM, EMPA and XRD. The wear resistance and corrosion resistance of the layer by laser cladding and laser cladding and sulfurizing were also studied. The results showed that phase composition of Ni-based alloy laser cladding coating mainly includes γ-(Fe, Ni), Fe0.64Ni0.36, M23C6, WC, M7C3 and Fe2B and so on, and its microstructure hardness is up to 740 HV0.2. Sulfide layer was produced on the Ni-based alloy coating with low temperature ion sulfurizing process, which is loose and porous, is piled up by the sharp island micro nan-scale particles. Compared with Ni-based alloy laser cladding layer, the friction coefficient and the wear loss of the modified composite layer decrease significantly, excellent antifriction and wear resistance can be obtained. After low temperature ion sulfurizing treatment, the corrosion potential decreases, and the corrosion current density increases and the corrosion resistance of Ni-based alloy laser cladding layer decreases slightly.
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    • 参考文献(16)
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  • 收稿日期:  2014-10-29

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