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控制气氛下的AgCuTi/TiAl润湿铺展动力学

Wetting kinetics of AgCuTi filler metal over the TiAl-based alloy substrate under controlled atmosphere conditions

  • 摘要: 采用热台原位加热法系统研究了不同保护气体流量对润湿铺展过程、润湿铺展最大半径、润湿铺展动力学以及界面组织结构的影响.保护气体为氩气,保护气体流量分别为5,10,15 mL/s;加热曲线设定最高温度为1273 K,保温时间120 s;采用扫描电镜、能谱分析、光学显微镜等分析了界面组织结构.结果表明,保护气体流量为15 mL/s时,润湿铺展等效半径最大,原始半径0.9 mm的钎料铺展半径达到约1.4 mm.各种保护条件下,AgCuTi/TiAl体系的润湿铺展动力学过程相似,铺展半径与时间之间呈n次幂关系,即rn~kt;润湿铺展中钎料熔敷/TiAl的界面结构为:残余钎料的富银相/AlCuTi三元相层(AlCu2Ti, AlCuTi, Ti3Al)/TiAl母材,保护条件对其影响不大.

     

    Abstract: Wetting kinetics of AgCuTi/TiAl brazing system under controlled atmosphere conditions were investigated assisted by a hot-stage microscopy system. Influence of the different shielding gas flow rate on the wetting process, the maximum radius during spreading process, wetting kinetics and interfacial microstructure were studied. Brazing of AgCuTi/TiAl system was conducted under the argon atmosphere with different gas flow rate of 5, 10 and 15 mL/s, respectively. The peak temperature and the dwelling time of the heating-cooling curve was 1273 K and 120 s, respectively. The interfacial microstructure was analyzed by using SEM, EDS and OM. The results showed that shielding gas flow rate had a great impact on the wetting/spreading phenomena:(i) maximum equivalent wetting radius of the molten filler was acquired when the shielding gas flow rate was 15 mL/s, i.e. a maximum radius of 1.4 mm was obtained from the original value of 0.9 mm after brazing;(ii) wetting process of AgCuTi/TiAl system under different protection conditions featured similar kinetics, which can be described using the classical Washburn model, and the radius during spreading showed the power function relationship vs. time, rn~kt; the protection conditions had little impact on the microstructure of the molten filler/TiAl, which features a layered-structure:Ag-rich phase of the residue filler metal/AlCuTi ternary intermetallics(AlCu2Ti, AlCuTi, Ti3Al) combined layer/TiAl substrate.

     

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