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温度对高速电弧喷涂FeNiBSi/Cr3C2复合涂层热腐蚀性能的影响

Effect of temperature on hot corrosion behavior of high velocity arc sprayed FeNiBSi/Cr3C2 coating

  • 摘要: 采用高速电弧喷涂技术在45钢基体上制备出FeNiBSi/Cr3C2复合涂层.采用光学显微镜和扫描电镜分析涂层的显微结构,以及X射线衍射分析涂层相组成.试验选用摩尔比为7:3的Na2SO4+K2SO4饱和水溶液为腐蚀介质涂刷于试样表面,并以20G钢作对比材料,在550~750℃下研究了涂层的抗热腐蚀性能.结果表明,涂层具有典型的层状结构特征,致密且连续.涂层的抗热腐蚀性能明显优于20G钢.在550和650℃下涂层表面形成了致密的氧化膜(Fe2O3, Cr2O3和FeCr2O4)阻碍了熔盐的侵入,提高了涂层抗热腐蚀性能.在750℃下涂层氧化膜变得不完整,不能有效地阻隔熔盐,此时涂层的抗热腐蚀性能较差.

     

    Abstract: The results show that the peak temperature remains at 500℃ in the FSW process and the highest temperature point appears in about 5 mm behind the tool. The residual stress of FS welded joint is mainly longitudinal stress. The longitudinal stress in the vertical direction of weld presents M type and the maximum is about 150 MPa. In the FSW process, when the rotation speed of the tool is constant, with the increasing of welding speed, the temperature decreases and the peak value of longitudinal residual stress increases. When the welding speed is constant, with the increasing of rotation speed, temperature increases. With the increasing of rotation speed, the distribution of longitudinal residual stress becomes more homogeneous.

     

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