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湿热环境对Zn-2Al钎料显微组织及力学性能的影响

Effect of hygrothermal environment on microstructure andmechanical properties of Zn-2Al filler metal

  • 摘要: 针对Zn-2Al钎料在湿热环境下的时效劣化行为,通过高温高湿加速腐蚀试验模拟了湿热大气环境,研究了在恒定湿热环境下腐蚀时间对钎料显微组织、力学性能及润湿性能的影响.结果表明,钎料表观腐蚀深度与腐蚀时间呈线性关系,水汽腐蚀主要发生在晶界处,当腐蚀达到一定程度后,钎料内形成了大量的腐蚀裂纹和腐蚀孔洞.晶间腐蚀是晶内富锌η相为阴极,晶界处富铝α相为阳极而溶解的电化学腐蚀.钎料的抗拉强度、塑性和韧性均随着腐蚀时间的延长而降低,钎料在1060铝板上的润湿面积随着腐蚀时间的增加而急剧减小.

     

    Abstract: The aging degradation behavior of Zn-2Al filler metal in hot and humid environment was studied. High temperature and high humidity accelerating test was conducted to simulate the hygrothermal atmospheric corrosion condition. The influence of corroding time on the microstructure, mechanical properties and wettability of Zn-2Al filler metal was investigated. The experimental results displayed linear relationship between corroding depth and corroding time. Water vapor corroding primarily occurred at grain boundaries, and when corrosion reached a certain extent, corrosion cracks and corrosion holes formed. This intergranular corrosion was electrochemical corrosion with the intragranular zinc-rich η phase as the cathode but the aluminumrich α phase as the anode that dissolute at grain boundary. The tensile strength, plasticity and toughness of Zn-2Al filler metal decreased, and the wetting area of Zn-2Al filler metal on 1060 aluminum sheet also decreased sharply with the increase of corroding time.

     

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