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DD3高温合金与Ti3AlC2陶瓷的真空钎焊

Study on vacuum brazing of DD3 Ni-base superalloy and Ti3AlC2 ceramic

  • 摘要: 通过对比试验优选出了合适钎料,并进行了后续钎焊试验.在钎焊温度800~900℃,保温时间为10 min的条件下,采用Ag-Cu-Ti钎料实现了DD3镍基高温合金与Ti3AlC2陶瓷的真空钎焊连接.利用扫描电镜、能谱仪、XRD等对接头的界面结构进行了分析.结果表明,接头的典型界面结构为DD3/AlNi/Al3(Ni,Cu)5+Al(Ni,Cu)+Agss/(Al,Ti)3(Ni,Cu)5/Al4Cu9+AlNi2Ti+Agss/TiAg/Ti3AlC2.接头的力学性能测试表明,在钎焊温度为850℃,保温时间为10 min的条件下,接头的最高抗剪强度可达135.9 MPa,断裂发生在靠近钎缝的Ti3AlC2陶瓷侧.降低和提高钎焊温度对接头界面组织影响不大,但接头强度有一定程度下降.

     

    Abstract: By comparison,an appropriate brazing filler metal was selected and applied to the follow-on experiments. DD3 Ni-base superalloy and Ti3AlC2 ceramic were successfully brazed in vacuum using Ag-Cu-Ti as filler metal in a temperature range of 800~900℃ for 10 min. The interfacial microstructure of the brazed joints was investigated by adopting scanning electron microscope,energy dispersive spectroscopy and X-ray diffraction. The result showed that the typical interfacial microstructure of the joints can be described as DD3/AlNi/Al3(Ni,Cu) 5+Al(Ni,Cu)+Agss/(Al,Ti)3(Ni,Cu)5/Al4Cu9+AlNi2Ti+Agss/TiAg/Ti3AlC2. Through the mechanical properties test of the joints,a maximum shear strength value of 135.9 MPa was obtained when the joint was brazed at 850℃ for 10 min. The fracture occurred at the Ti3AlC2 ceramic side adjacent to the brazed seam during the shear test. The interfacial microstructure of the joints was similar to each other,while the shear strength decreased when reduces or improves the brazing temperature.

     

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