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热时效过程中微米级SnAgCu焊点的界面金属间化合物形成及演变

Interfacial IMC evolution in micron Sn-Ag-Cu soldered joint during thermal aging

  • 摘要: 研究微米级倒装组装焊点在150℃热时效过程中界面金属间化合物(intermetalic compound,IMC)的形成及演化.结果表明,在热时效300 h后,受铜焊盘界面扩散过来的Cu原子影响,镍焊盘界面(Ni,Cu)3Sn4全部转化成(Cu,Ni)6Sn5;在铜焊盘界面,热时效至100 h后,形成一层薄的Cu3Sn,在随后的热时效过程中,由于Ni原子对Cu3Sn生长的抑制作用,Cu3Sn几乎没有生长.此外在时效100 h内,两侧界面(Cu,Ni)6Sn5生长速率增加较快,但随着时效时间的增加逐渐减慢.两侧界面(Cu,Ni)6Sn5顶端形貌随着时效时间的增加逐渐变平.

     

    Abstract: The interfacial intermetallic compound(IMC) evolution in micro-soldered joints in thermal aging process of flipchip assemblies was investigated.The results show that all (Ni, Cu)3Sn4 on the Ni pad interface are transformed into (Cu, Ni)6Sn5 after 300 h for thermal aging due to the effect of Cu atoms diffused from the Cu pad interface on the (Ni,Cu)3Sn4.On the Cu pad interface,a thin layer of Cu3Sn forms on the interface between the Cu pad and (Cu,Ni)6Sn5 after 100 h for aging, however in the subsequent thermal aging,Cu3Sn experiences little growth because of the limitation effect of Ni on its growth.The growth rate of (Cu,Ni)6Sn5 on the both pad interfaces are fast before 100 h,and after 100 h,it become slower and slower.Furthermore,as the aging time increases,the interface of (Cu, Ni)6Sn5 grain inclines to be flat.

     

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