CuZnSnSi合金钎料相变过程的热分析动力学
Thermal kinetics for phase transformation of CuZnSnSi alloy
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摘要: CuZnSnSi合金钎料在钎焊钢工件中具有良好的综合性能.为进一步探究其合金性能,借助差示扫描分析(DSC)和热重分析(TG)技术,分别采用微分非等温法和积分非等温法分析了CuZnSnSi合金钎料相变过程的热分析动力学.结果表明,CuZnSnSi合金的相变温度范围为1150.5~1221.5 K,吸热峰温度为1174.46 K,在相变过程中没有化学反应,但出现升温段的吸热峰温度滞后于降温段的放热峰,说明了合金钎料在结晶过程需要一定的过冷度;非等温分析法计算得到合金钎料相变表观活化能为615.72 kJ/mol;由Arrhenius公式得出合金钎料相变速率常数k的变化规律为1.71×1027exp(-6.16×105/RT).Abstract: A study on fluid flow in the molten pool of laser deep penetration welding process was carried out which utilized the finite volume method.A three dimensional fluid flow model was established and the effect of the laser beam was represented by the Gaussian rotating body heat source.The temperature field,fluid flow and weld shape were calculated considering the Marangoni effect.The temperature field contours,the welding thermal cycle curve of molten pool and the velocity field of molten pool were analyzed based on the calculated results.Finally, the laser welding experiment was carried out with the same weld parameters.The actual weld shape was observed.The simulation results and experiment results were comprehensively analyzed.The accuracy of the numerical simulation results was verified.The calculated geometries of the molten pool and welds were more similar to that of the experimental results when the Marangoni convection was considered.