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颗粒增强复合钎料钎焊TiAl合金接头界面结构及性能

Interfacial microstructure and properties of TiAl joints brazed with composite filler reinforced by particles

  • 摘要: 采用纳米Si3N4颗粒增强的AgCuTi复合钎料(AgCuTiC)实现了TiAl合金的钎焊连接.利用SEM,EDS及XRD等分析方法确定了TiAl/AgCuTiC/TiAl接头的典型界面结构为TiAl/AlCu2Ti/Ag(s,s)+TiN+Al4Cu9+Ti5Si3.结果表明,钎焊过程中从TiAl母材溶入液相钎料的活性钛与复合钎料中纳米Si3N4颗粒发生反应,在钎缝中形成了细小的颗粒状TiN,Ti5Si3及Al4Cu9化合物增强的银基复合材料组织.银基复合材料的形成不仅提高了钎缝自身的强度,而且通过降低钎缝的线膨胀系数缓解了接头残余应力,并最终改善了钎焊接头的性能.当采用增强相含量为3%的AgCuTiC钎料在880℃保温5 min条件下钎焊时,接头室温平均抗剪强度最高为278 MPa,比采用AgCuTi钎料提高40%.

     

    Abstract: Interfacial microstructure and properties of TiAl joints brazed with composite filler reinforced by particlesTiAl alloy was brazed with AgCuTiC composite filler metal reinforced by nano-Si3N4 particles.The typical interfacial microstructures in TiAl/AgCuTiC/TiAl joint are TiAl/Al- Cu2Ti/Ag(s,s)+TiN+Al4Cu9+Ti5Si3,which are analyzed by SEM,EDS and XRD.Investigation results indicate that the active element Ti dissolves from TiAl substrate and reacts with nano-Si3N4 to form fine compounds including TiN,Ti5Si3 and Al4Cu9 during brazing process.These compounds are uniformly distributed in Ag solid solution,which lead to the formation of Ag based composite in brazed seam.The desired microstructure can not only strengthen the brazed seam,but also reduce the residual stresses in joints by decreasing the mismatch of coefficient of thermal expansion between TiAl substrate and brazing seam, which greatly improves the joint properties.The maximum shear strength of 278 MPa can be obtained with AgCuTiC composite filler with 3% nano-Si3N4 addition at 880℃ for 5 min,which is 40% higher than that brazed joint using AgCuTi directly.

     

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