SnAgCu/Cu钎焊接头等温时效下组织性能分析
Microstructure and mechanical properties of SnAgCu/Cu solder joint during isothermal aging
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摘要: Sn3.0Ag0.5Cu/Cu钎焊接头在125,150,175℃三种温度下分别进行了36,72,216,360,720 h等温时效,对钎焊接头微观组织及力学性能在时效过程中的演变规律进行了研究.结果表明,界面金属间化合物(IMC)在横截面上呈细小锯齿状,随着时效温度升高及时间延长,界面IMC的尺寸不断增加,增长速度随时效温度升高而增加,随时效时间延长而减小.界面IMC齿数不断减少、齿径变大、齿高变长、齿距变宽.分析得出一种科学的表征界面IMC尺寸的方法.计算时效后界面IMC层等效厚度,发现界面IMC层的等效厚度与时效时间及温度之间具有一定的数学关系,同时可计算出界面IMC的生长激活能为88 kJ/mol.此外研究了时效对钎焊接头抗拉强度的影响,随时效时间增加接头抗拉强度先增大后减小,这主要与接头残余应力释放及界面IMC的演变有关.Abstract: The Sn3.0Ag0.5Cu/Cu lead-free solder and Cu joints were isothermally aged at 125,150 and 175℃ for 36,72,216,360 and 720 h. The microstructure and mechanical properties of the solder joints were studied. The results showed, after soldering the interfacial intermetallic compounds (IMC) of solder joints were small serrate. The size of interfacial IMC was found to increase with the aging temperature and aging time. The IMC growth rate increased with aging temperature but decreased with aging time. With the increase of aging time,the amount of IMC serration decreased,and its diameter,height and width became bigger,higher and wider respectively. Through analysis of the interfacial IMC,a scientific method to characterify IMC size was found. When the IMC equivalent thickness was calculated, the quantitative relationship between IMC equivalent thickness and aging time/temperature was established. The IMC activation energy is 88 kJ/mol. In addition,the relationship between isothermal aging and tensile strength was developed. The tensile strength firstly increased and then decreased with the aging time, which could be attributed to the welding residual stress relaxation and the IMC evolution.