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原位合成TiC和M7C3陶瓷硬质相的生长习性

Growth habit of TiC and M_7C_3 ceramic hard phase in situ synthesized

  • 摘要: 采用等离子弧堆焊设备在低碳钢表面堆焊一层Fe-Cr-Ti-C系陶瓷复合堆焊合金,原位合成TiC和M7C3陶瓷硬质相,分析熔池中TiC和M7C3陶瓷硬质相的形成机制.利用X射线衍射仪(XRD)、扫描电镜(SEM)、能谱分析仪(EDS)等设备进行检测分析.结果表明,堆焊层中原位合成了"十字开花状"、"短杆状"、"颗粒状"的TiC陶瓷硬质相和不规则"六角杆状"的M7C3陶瓷硬质相;部分TiC和M7C3陶瓷硬质相紧密结合,提高了TiC陶瓷硬质相与基体组织的结合强度;M7C3可以附着在TiC颗粒上生长,TiC硬质相的形成提高了M7C3的形核率.

     

    Abstract: Plasma welding technology was used to melt the Fe-Cr-Ti-C system wear-resistant alloy on the low-carbon steel, TiC and M7C3 were in situ synthesized in the surfacing layer, and the formation mechanism of TiC and M7C3 ceramic hard phase in the weld pool was studied.X-ray diffraction(XRD), scanning electron microscope(SEM), spectrum analyzer(EDS) were used to test the microstructure of the surfacing layer.The result shows that a large number of cross flower-shaped, short rod-shaped, granular TiC ceramic hard phase and hexagonal rod-shaped M7C3 ceramic hard phase are formed in the surfacing layer.Part of the TiC and M7C3 ceramic hard phase work closely together and the bonding strength between the ceramic hard phase of TiC and matrix structure is improved.The M7C3 grains could form next to the TiC ceramic hard phase, and formation of TiC hard phase improves the nucleation rate of M7C3 hard phase.

     

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