2205双相不锈钢焊接接头微区耐点蚀性能分析
Pitting corrosion resistance of micro-zones in welded joint of 2205 duplex stainless steel
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摘要: 采用光学显微镜观察了2205双相不锈钢焊接接头的组织形貌,采用自制的微电化学测试系统测量了母材、焊缝和HAZ的微区循环伏安曲线.结果表明,2205双相不锈钢焊接接头的组织为铁素体+奥氏体,焊缝中铁素体含量约为48%,与母材相当,HAZ中铁素体平均含量高于50%;在3.5%的NaCl溶液中2205双相不锈钢焊接接头焊缝微区的耐点蚀性能与母材趋于一致,但其自修复能力不及母材,HAZ微区的耐点蚀性能最差,自修复能力最弱,此耐点蚀性能上的差异与接头中两相比例和合金元素在两相中的分配差异有关.Abstract: The microstructures of welded joint of 2205 duplex stainless steel were studied by optical microscope. Cyclic voltammetry curves of base material,weld metal and HAZ were measured by a self-designed micro electrochemical system respectively. The results show that the microstructures of welded joint of 2205 duplex stainless steel are ferrite and austenite. The percentage of ferrite in weld metal is about 48%,which is equivalent with that in base material,while the average ferrite content in HAZ is more than a half. In the 3.5% NaCl solution,the weld metal shows the consistent pitting corrosion resistance with the base material,but its repassivation behavior is not as good as the base material. Among the three micro-zones of the welded joint,HAZ shows the poorest pitting corrosion resistance and repassivation behavior. The differences on pitting corrosion resistance of different micro-zones of welded joint are relevant to the phase ratio and the distribution of alloy elements in phases.