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微量B元素对Cu-P基急冷钎料润湿性的影响

Effect of micro B on wettability of Cu-P based quenching filler metals

  • 摘要: 采用单辊急冷装置成功制备了三种成分的Cu-P基合金钎料箔带,采用DTA和XRD等手段分析其熔化特性和结构,并对其在紫铜上的铺展性进行研究.结果表明,和同成分的常规钎料相比,急冷钎料的液固相线温度降低,熔化区间变窄.其中B元素含量0.03%的急冷钎料具有最低的液相线温度和最窄的熔化温度区间.B元素含量为0.02%和0.03%的急冷钎料结构为非晶.在相同工艺条件下,B元素含量为0.03%的急冷钎料在紫铜上的润湿性最好;随着钎焊温度提高或钎焊时间的增加,Cu-P基急冷钎料的润湿性都出现了先增大后减小的趋势;急冷钎料和常规钎料相比,润湿性明显提高.

     

    Abstract: Three different components of the Cu-P based filler metal foils were prepared by single-roll rapidly-cooled equipment. The melting feature and structure were analyzed with DTA and XRD methods. The wettability of Cu-P based filler metals on copper was studied. The results showed that, compared with the conventional filler metals, the quenching filler metals had lower melting temperature and narrower melting temperature range. The quenching filler metal containing 0.03% B had the lowest liquidus temperature and the narrowest melting temperature range. The structures of the quenching filler metals with 0.03wt% B and 0.04% B were amorphous. In the same process conditions, the quenching filler metal contained 0.03wt% B had best wettability on copper. As with brazing temperature and time increased, the wettability of Cu-P based quenching filler metal appears increased first and then decreased. Compared with conventional brazing filler metals, the wettability of quenching filler metal has been improved significantly.

     

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