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Al2O3-TiC复合陶瓷与Q235钢扩散连接界面组织结构

Microstructure of Al2O3-TiC composite ceramics and Q235 steel diffusion bonded interface

  • 摘要: 采用Ti/Cu/Ti复合中间层通过液相扩散连接技术实现了Al2O3-TiC复合陶瓷与Q235低碳钢的扩散连接.采用扫描电镜、电子探针及X射线衍射等测试手段对Al2O3-TiC/Q235扩散连接接头的显微组织、断口形貌及相组成进行了分析.结果表明,Al2O3-TiC/Q235界面结合紧密,没有显微孔洞、裂纹及未连接区域;Al2O3-TiC/Q235界面附近有各种各样的新相生成,如TiO,Ti3Al,Cu2Ti4O及Cu3Ti3O,所生成的TiO相及复杂结构氧化物Cu3Ti3O和Cu2Ti4O都具有金属特性,对于促进Al2O3-TiC/Q235的可靠连接起到重要作用;接头抗剪强度达143MPa,断口表现为脆性断裂特征,Al2O3-TiC/Q235接头断在界面附近的Al2O3-TiC内.

     

    Abstract: The diffusion bonding of Al2O3-TiC composite ceramics to Q235 low carbon steel by using Ti/Cu/Ti as multi-interlayer was carried out by liquid phase diffusion bonding technology.The microstructure,fracture morphology and phase constituents for Al2O3-TiC/Q235 diffusion bonded joint were studied with scanning electron microscope,electron probe microanalysis and X-ray diffraction.The test results indicate that the Al2O3-TiC composite ceramics tightly combines with Q235 low carbon steel,and the interface both on the Al2O3-TiC and Q235 side seems to be continuous,straight and free of the micro-voids,cracks and unbonded areas.The various new phases,such as TiO,Ti3Al,Cu2Ti4O and Cu3Ti3O,are formed near the interface of the Al2O3-TiC/Q235 joint.The formed TiO phase and the complex structure oxides of Cu2Ti4O and Cu3Ti3O have metallic characteristics,which are very important to promote reliable bonding of Al2O3-TiC with Q235.The shear strength of the joints reaches 143 MPa,the fracture reveals brittle features and the fracture of the Al2O3-TiC/Q235 joint occurs in Al2O3-TiC near the interface.

     

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