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陶瓷/AgCuTi/不锈钢钎焊连接界面组织与结构

Interface structuce of ceramic/AgCuTi/stainless steel brazed joint

  • 摘要: 采用Ag-Cu-Ti钎料对日用陶瓷与1Cr18Ni9Ti不锈钢进行了钎焊连接.用扫描电镜、能谱仪以及X射线衍射仪对接头的微观组织形貌、特征点的成分以及钎焊接头的物相等进行了分析研究.结果表明,接头界面处形成了多种化合物,包括TiO,TiSi2,Ti5Si3和Fe2Ti.当温度为850℃,保温时间为5min时,接头界面结构为1Cr18Ni9Ti不锈钢/Fe2Ti/Ags,s+Cus,s+Fe2Ti/TiO+Ti5Si3+TiSi2/陶瓷.当钎焊温度较高或保温时间较长时,界面反应层厚度增加,界面中基体相Ags,s,Cus,s所占比例显著减小.

     

    Abstract: Domestic ceramics and 1Cr18Ni9Ti stainless steel were brazed using Ag-Cu-Ti filler metal. Microstructure, the component of characteristic points and the phases of brazing joints were studied by scanning electronic microscopy (SEM), energy distribution spectrometer (EDS) and x-ray diffraction (XRD). The results show that several kinds of intermetallics such as TiO2, TiO, TiSi2, Ti5Si3 and Fe2Ti were formed. The interfacial structure of joints is 1Cr18Ni9Ti stainless steel/Fe2Ti/Ags, s+Cus, s+Fe2Ti/TiO2+TiO+Ti5Si3+TiSi2/ceramics when brazing temperature and time are 850℃ and 5min, respectively. The depth of interfacial reactive layer increases and the ratio of matrix phase Ags, s, Cus, s which are in the middle of interface reduces evidently as brazing temperature is very high or holding time is very long.

     

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