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稀土Y加速Sn晶须生长规律

Study of tin whisker growth accelerated by rare earth Y

  • 摘要: 氧原子向稀土相YSn3晶格内部的扩散使YSn3产生体积膨胀,而周围钎料基体对体积膨胀的抑制作用使其内部产生巨大的压应力,此压应力为Sn晶须的生长提供了驱动力;与此同时,稀土相YSn3氧化过程中释放出的自由Sn原子为Sn晶须的生长提供了生长源.对空气中室温与150℃时效条件下稀土相YSn3表面Sn晶须的生长进行了研究.结果表明,室温时效条件下,稀土相YSn3表面Sn晶须的生长速度缓慢且分布不均;高温时效条件下,稀土相YSn3表面Sn晶须的生长速度较快且巨大的压应力使钎料基体发生了隆起现象。

     

    Abstract: It is known that rare-earth elements exhibit high chemical activity and adding trace amount of rare-earth(RE) in the solder can significantly improve the properties of solder alloy.However, RE-phases with large size precipitated in the Sn-3.8Ag-0.7Cu-1.0 RE solder alloy are oxidized when exposed in air, tin whiskers growing rapidly on the surface of the oxidized RE-phases.Tin whisker growth on the surface of the oxidized YSn3 phase is investigated at room temperature and 150℃ storage in air respectively.The results indicate that tin whiskers grow slowly and distribute unevenly on the surface of the oxidized YSn3 phases during room temperature storage in air, but tin whiskers grow rapidly and the YSn3 phase is extruded around even solder matrix during 150℃ storage in air.

     

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