纯铝微弧氧化陶瓷膜组织及耐腐蚀性能
Structure and electrochemistry corrosion behaviors of microarc oxidation on aluminum
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摘要: 利用微弧氧化技术,在碱性硅酸盐电解液中对纯铝进行表面改性处理,制备均匀致密的陶瓷膜。利用扫描电子显微镜(SEM)观察氧化陶瓷膜表面形貌及横截面组织结构,利用纳米压入硬度测试仪测量陶瓷膜的显微硬度和杨氏模量的分布,运用电化学方法测量陶瓷膜的耐腐蚀性能。结果表明,铝合金微弧氧化陶瓷膜的表面硬度高达25.3GPa,纳米硬度和杨氏模量在陶瓷膜的横截面分布相似,从膜基结合处向膜层表面呈下降趋势。从极化曲线中的腐蚀电势和腐蚀电流来看,微弧氧化处理后,纯铝的抗腐蚀能力得到很大的提高。Abstract: The thick, dense and ultra-hard ceramic coating was obtained on the aluminum surface in a silicate electrolyte by microarc oxidation.The surface morphology and cross section of ceramic coating were observed by SEM, the hardness and Young's modulus of ceramic coating were estimated by nano-hardness tester, and the electrochemistry corrosion behaviors of ceramic coating were evaluated using polarization curves.The results show that the highest surface hardness of ceramic surface coating is 25.3 GPa;the hardness and Young's modulus of cross section of coating distribute similarly, both of them decrease from interface to surface of the coating; from the results of electrochemistry, microarc oxidation is effective method to form an anti-corrosion protective film on aluminum.