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何宜柱, 卢云. 激光熔覆原位合成Cop/Cu复合涂层[J]. 焊接学报, 2008, (3): 1-4.
引用本文: 何宜柱, 卢云. 激光熔覆原位合成Cop/Cu复合涂层[J]. 焊接学报, 2008, (3): 1-4.
HE Yizhu, LU Yun. In-situ synthesis of Cop Cu composite coating by laser cladding[J]. TRANSACTIONS OF THE CHINA WELDING INSTITUTION, 2008, (3): 1-4.
Citation: HE Yizhu, LU Yun. In-situ synthesis of Cop Cu composite coating by laser cladding[J]. TRANSACTIONS OF THE CHINA WELDING INSTITUTION, 2008, (3): 1-4.

激光熔覆原位合成Cop/Cu复合涂层

In-situ synthesis of Cop Cu composite coating by laser cladding

  • 摘要: 采用激光熔覆快速凝固技术,原位合成了Cop/Cu复合材料涂层,应用扫描电镜及能谱附件研究了激光工艺参数对涂层显微组织的影响。结果表明,激光熔池大的过冷度条件,有利于Cu-Co合金的液相分离。在优化的激光熔覆工艺条件下,可原位合成表面光滑、均匀连续的致密Cop/Cu复合涂层,涂层组织由大量细小的均匀分布在铜基固溶体基体上的富γ-Co球形颗粒组成。随着热输入的降低,颗粒相的尺寸得到细化。对Co/Cu复合涂层组织的形成和细化机理进行了分析。

     

    Abstract: Uniform Cop/Cu composite coatings were fabricated by laser cladding and rapid solidification technique, and the influences of processing parameters on microstructure were investigated by scanning electron microscope and energy dispersive spectroscopy. The results showed that high undercooling in the laser melting pool was helpful to the liquid phase separation of Cu-Co alloy.Cop/Cu composite coating with smooth surface can be successfully in situ synthesized when the processing conditions were well controlled.The as-solidified microstructures were characterized by a distribution of small spherical Co-rich particles homogeneously dispersed in the Curich matrix.Cop/Cu coating was consisted ofγ-Co and Cu-rich solution.With the decreasing of laser heat input, the diameters of spherical particles in coating decreased.The microstructural evolution and refining mechanism of the Cop/Cu coatings were also discussed.

     

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