Cr与B对镍基高温钎料在Cf/SiC陶瓷基复合材料上润湿性的影响
Influence of chromium and boron on wettability of nickel-based high temperature filler metal on Cf/SiC ceramic matrix composite
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摘要: 研究了Cr和B元素对镍基高温钎料在3D-Cf/SiC陶瓷基复合材料上的润湿性的影响。试验结果发现,在真空度小于10-3 Pa,工作温度1100℃,保温时间10 min条件下,当钎料中的Cr元素含量为15%,B元素含量为0.6%时,镍基钎料在Cf/SiC上的润湿角为10°,然而B元素含量增加到2.4%后,润湿角增大到62°,表明钎料中的元素B降低钎料在Cf/SiC上的润湿性。钎料中的活性元素Cr对润湿有重要影响。镍基钎料在Cf/SiC上的润湿过程属于反应润湿,润湿界面生成多种碳化物和硅化物。采用扫描电镜与能谱仪分析界面的微观结构与成分,通过X射线衍射仪检测界面产物。Abstract: The influence of boron and chromium on wettability of nickel-based high temperature filler metals on carbon fiber reinforced silicon carbide composite (3D-Cf/SiC)was studied.It was found that at 1 200℃ for 10 min under vacuum when the content (wt,%)of chromium equals to 15% and boron equals to 0.6%, the contact angle of nickel based filler metal on Cf/SiC is 10 degree. While, as the content of boron adds to 2.4%, the angle increases to 62 degree.It indicates the boron reduces thewettability.The experiment results indicates the element chromium can promote wettability greatly.The wetting procedure is reactive wetting, and several carbides and silicides were formed at interface.