电火花沉积反应合成TiN增强金属基复合涂层
Reactive synthesis TiN reinforced matrix composite coating by electric-spark deposition
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摘要: 利用自制的电火花沉积充气密闭式保护装置和DZ-1400型电火花沉积机,以工业纯钛TA2为电极,以工业纯氮为保护气和反应气,在45钢试件表面上电火花沉积反应合成制备了TiN增强金属基陶瓷复合涂层。利用X射线衍射仪测定了涂层的物相组成,利用扫描电子显微镜观察分析了涂层的显微组织结构,利用硬度仪测试了涂层的显微硬度,利用自制磨损试验装置对比了涂层与淬火W18Cr4V高速钢的耐磨性能。结果表明,涂层与基体结合致密,涂层主要由电极材料钛、原位自生的TiN和基体材料铁组成,涂层的平均显微硬度可达1323HV0.1,涂层具有较好的耐磨性。Abstract: TiN metal matrix composite coating was deposited on 45 steel substrate with the home-made special gas-filled-closed electric-spark deposition device and electric-spark deposition machine modeled DZ-1400, and the industry pure titanium (TA2) was used for electrode and the industry pure nitrogen for shielding and reactive gas.The phase of coatings was analyzed using X-ray diffractometer.The microstructure of coatings was investigated with scanning electron microscope.The microhardness of coatings was tested by hardness-testing device.The wear-resisting property of coatings was compared with that of W18Cr4V rapid steel treated by quenching using the home-made abrasion machine.The results indicated that excellent bonding between the coating and the carbon steel substrate is ensured by the strong metallurgical interface.The coatings was mainly made up of Ti coming from electrode, TiN ceramic particle synthesized in-situ and Fe coming from substrate.The average microhardness of coating is 1 323 HV0.1 and its wear-resisting property is better than that of W18Cr4V rapid steel treated by quenching.