焊缝针状铁素体中温转变机制的热力学分析
Thermodynamic analysis on intermediate transformation mechanism of acicular ferrite in welds
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摘要: 基于预相变形成奥氏体贫碳区的特点,采用KRC活度模型和超组元算法,分别建立了Fe-C-X系微合金焊缝针状铁素体在奥氏体贫碳区扩散和切变转变的两种相变热力学模型,并针对某种微合金钢成分进行了数值计算。结果表明,贫碳区成分不同而表现出不同的相变机制倾向。当奥氏体贫碳区C元素含量较高时,焊缝针状铁素体扩散模型的相变驱动力较大;而贫碳区C元素含量较低时,切变模型的相变驱动力又稍微大些;在贫碳区C元素含量为零的极限条件下,两模型的相变驱动力相等。两种模型的相变驱动力均具有相同的变化规律,即随着奥氏体贫碳区C元素含量的降低而增加,随着相变温度的降低而增加。Abstract: Based on the fact that carbon-depleted regions come into being during the incubation period, thermodynamic models of diffusion and shear for weld acicular ferrite(AF)transformation in carbon-depleted regions of austenite were established respectively by using KRC (Kaufman, Radcliffe, Cohen)activity model and superelement algorithm, and used in the numerical simulation of a certain microalloy steel.The results show that with the variation of carbon content in the carbon-depleted region, the transformation mechanism of AF is different.The driving force in diffusion model is greater than that of shear model when the carbon content is much higher, while the driving force in shear model is a little greater than that of diffusion model when the carbon content is much lower.If there is no carbon in the carbon-depleted region, the driving forces of both models will be equal.The driving forces of the two models show the similar tendency, and increase with the decreasing of carbon content in carbon-depleted regions and AF transformation temperature.