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SnPb钎料与Au/Ni/Cu焊盘反应过程中Au的分布

Distribution of Au during reaction of eutectic SnPb solder and Au/Ni/Cu pad

  • 摘要: 采用熔融的共晶锡铅钎料熔滴与Au/Ni/Cu焊盘瞬时接触液固反应形成钎料凸点,随后进行再流焊及老化。对这一过程中的钎料/焊盘界面金属间化合物组织的演化,尤其是Au-Sn化合物的形成及分布进行了研究。结果表明,钎料熔滴与焊盘液固反应形成了Au-Sn界面化合物,铜层未完全反应。在随后的再流焊过程中,界面处的铜层完全消耗掉,镍层与钎料反应形成Ni3Sn4界面组织;针状的AuSn4化合物分布于钎料基体中。老化条件下分布于钎料基体中的AuSn4重新在界面沉积,在Ni3Sn4层上形成(AuxNi1-x)Sn4层。(AuxNi1-x)Sn4在界面的沉积遵循分解扩散机制,并促进富铅相的形成。钎料与焊盘反应过程中Au-Sn化合物的演化及分布直接影响钎料与焊盘的连接强度。

     

    Abstract: Solder bump was fabricated with Sn-Pb eutectic solder droplet on Au/Ni/Cu pad.The solder/pad was then subject to reflow soldering and aging at 125℃.The IMC evolution at solder/pad interface during this process,especially the formation and distribution of Au-Sn compound were investigated.The results showed that Au-Sn compound forms at solder/pad interface during contact reaction,and Au does not re-act fully with solder droplet.During the subsequent reflow soldering,all Au layer at interface is consumed,Ni layer reacts with solder,which leads to the formation of Ni3Sn4 compound at the interface.Acicular AuSn4 can be found in the solder bulk.AuSn4 particles redesposites at the interface as a continuously(AuxNi1-x) Sn4 layer during aging at 125℃.The redesposited(AuxNi1-x) Sn4 at solder/pad interface follows decomposition-diffusion mechanism.At the same time,a lead-rich phase emerges with AuSn4 redeposition at the interface.The shear strength of soldered joint is mainly determined by this evolution and distribution of Au-Sn compound.

     

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