Ti/Cu共晶反应液相铺展及组织
Liquid spreading and micro structure of Ti/Cu eutectic reaction
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摘要: 对Ti/Cu共晶反应偶液相铺展及组织进行了初步研究。结果表明,不同的基体或反应材料,共晶液相表面铺展现象显著不同。当Ti为基体时,共晶液相铺展区域呈较规则的圆形,并且接触角较小,而当Cu为基体时,铺展形状不规则,且有溶蚀现象;不同组合的Ti/Cu共晶反应偶对共晶液相产生及铺展速度将会产生影响,当Ti为基体、Cu为反应材料时,Cu的溶解速度较快,在试验条件下,保温时间120s,Cu粒已完全溶解,而相同条件下Ti粒溶解则需要2100s;Ti/Cu/Ti接触反应钎焊接头中形成的金属间化合物为TiCu、Ti3Cu4、Ti2Cu、TiCu4。Abstract: The liquid spreading and structure of Ti/Cu eutectic reaction couples were primarily studied.The results showed that the spreading behaviors are remarkably different with the varied base metals and reactants.When Ti as the base metal,the spreading zone of the eutectic liquid phase is relatively regular circle-like and the contact angle is smaller.When Cu as the base metal,the spreading zone of the eutectic liquid phase is not regular a resorption phenemenon appears.Different assembled Ti/Cu eutectic reaction couples will affect the formation and spreading rate of the liquid when Ti as the base metal and Cu as the reactant.The dissolution of Cu is quick under the condition of this work,and Cu particle is dissolved completely with holding time of 120 s,but it will spend 2 100 s for Ti particle dissolved entirely at the same condition.The intermatallic compounds are TiCu、Ti3Cu4、Ti2Cu and TiCu4 Ti/Cu/Ti contact reactive brazing.