高级检索

预充氢对SCR焊接接头应力腐蚀敏感性影响

The influence of hydrogen pre-charging on the stress corrosion susceptibility of SCR welded joints

  • 摘要: 文中通过对X65制钢悬链线立管(steel catenary riser,SCR)焊接接头进行微观组织分析、慢应变速率拉伸试验(slow strain rate test,SSRT)及断口分析,探究预充氢对SCR应力腐蚀开裂(stress corrosion cracking, SCC)敏感性的影响. 结果表明,焊接接头热影响区中,细晶热影响区(fine-grained heat-affected zone,FGHAZ)主要由细小且均匀的铁素体(ferrite, F)和珠光体(pearlite, P)组成,使该区域力学性能显著优于其他热影响区域,而粗晶热影响区(coarse-grained heat-affected zone,CGHAZ)主要包括大块的先共析铁素体(proeutectoid ferrite,PF)、M-A组元等组织,使得该处抗SCC性能较差. SSRT试样在不同预充氢时间的条件下,应力−应变曲线的弹性阶段几乎重合,但预充氢使得试样抗拉强度降低. 此外,NaCl溶液腐蚀环境试样未充氢及充氢4天的应力腐蚀敏感性系数EZ分别为0.67%和11.14%;H2S腐蚀环境试样未充氢及预充氢4天的应力腐蚀敏感性系数EZ值分别为11.96%和46.38%,证明两种腐蚀环境下预充氢均会降低焊接接头的抗SCC能力. 试样在空气环境中发生韧性断裂,在两种腐蚀环境主要发生准解理断裂,预充氢使材料韧性降低,断口附近的微裂纹和孔洞现象加剧,降低了材料的抗SCC性能.

     

    Abstract: This study shows the influence of hydrogen pre-charging on the stress corrosion cracking (SCC) susceptibility of steel catenary riser (SCR) welded joints made of X65 through microstructural analysis, slow strain rate tensile test (SSRT) , and fracture surface analysis. The results reveal that the fine-grained heat-affected zone (FGHAZ) of the welded joints primarily comprises fine and uniform ferrite (F) and pearlite (P), significantly enhancing the mechanical property of this zone compared to other heat-affected zone . In contrast, the coarse-grained heat-affected zone (CGHAZ) is characterized by large block of proeutectoid ferrite (PF) and M-A constituent, resulting in poor SCC resistance in this area. Although the elastic stage of the stress-strain curve of SSRT sample under various hydrogen pre-charging time nearly coincide, hydrogen pre-charging decreases the tensile strength of the samples. Additionally, in a NaCl solution corrosion environment, the stress corrosion susceptibility coefficient EZ of the samples hydrogen uncharged and after four days of hydrogen pre-charging are 0.67% and 11.14%, respectively; in an H₂S corrosion environment, the stress corrosion susceptibility coefficient EZ values for the samples hydrogen uncharged and after four days of hydrogen pre-charging are 11.96% and 46.38%, respectively. This demonstrates that hydrogen pre-charging reduces the SCC resistance of welded joints in both corrosion environment. The samples undergo ductile fracture in the air environment, while quasi-cleavage fracture predominates in both corrosion environment. Hydrogen pre-charging reduces the material toughness and exacerbates microcracks and hole near the fracture surface, thereby reducing the material's resistance to SCC.

     

/

返回文章
返回