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SiC- Cu钎焊接头的低温连接工艺及组织性能

Soldering process of the SiC-Cu joint and its microstructure and properties

  • 摘要: 为了研究基于高功率碳化硅器件的低温封装应用需求,开发了碳化硅陶瓷与散热铜板的低温连接工艺. 首先通过磁控溅射技术对碳化硅(SiC)进行表面金属化处理,再采用Sn基钎料对碳化硅和无氧铜进行低温真空钎焊,从而实现了SiC-Cu的钎焊连接,分析并揭示了碳化硅表面的金属化层厚度,以及Sn基钎料的成分对SiC-Cu钎焊接头组织和力学性能的影响. 结果表明,SiC-Cu钎焊接头的结合强度与母材SiC一侧界面处冶金反应的程度直接相关,受Sn基钎料成分及SiC表面金属化Cu层厚度的影响,当采用SnCu钎料时,钎焊接头中靠近SiC界面处冶金反应较为充分,生成的金属间化合物主要为Cu6Sn5,且随着Cu层厚度的增加反应产物逐渐增多,接头结合强度不断提高,当Cu层厚度达到2000 nm时,SiC-Cu钎焊接头的结合强度可达峰值14 MPa左右.

     

    Abstract: Research on the application requirements of low-temperature packaging based on high-power SiC devices, and develop a low-temperature connection process between SiC ceramics and heat dissipation Cu plates. The SiC-Cu brazing joint was successfully achieved by surface metallization of silicon carbide through magnetron sputtering technology and low-temperature vacuum soldering with Sn-based fillers. The influence of the thickness of metallized Cu layer on SiC and the composition of the Sn-based fillers on microstructure and mechanical properties of the SiC-Cu joint was analyzed and realized. It is proposed that the shear strength of SiC-Cu joints depends on the degree of metallurgical reaction close to the boundary between SiC and Sn-based fillers, which is influenced by the composition of Sn-based filler and the thickness of the metallized Cu layer on the surface of SiC. In general, the SnCu alloy was recommended to serve as the filler due to its nice metallurgical reaction wtih the Cu film on SiC. In this case, the intermetallic compound (IMC) near SiC in the SiC-Cu joint is mainly Cu6Sn5 and its quantity increases with the increasing thickness of the Cu film, leading to the improvement of shear strength of the joint. As a result, the SiC-Cu joint soldered by SnCu filler has a peak shear strength of about 14 MPa when the thickness of Cu film on surface of SiC is about 2000 nm.

     

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