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Sn-58Bi微焊点组织与力学性能的尺寸效应行为

Size effect behavior of microstructure and mechanical properties in Sn-58Bi micro solder joints

  • 摘要: 研究了回流焊点尺寸的减小对Sn-58Bi焊点显微组织形貌的影响,分析了在不同老化时间下焊点尺寸的减小对焊点界面微观组织的演变和剪切性能的影响. 结果表明,在相同的冷却条件下,焊点尺寸的减小造成焊点在凝固阶段有较大的过冷度,在焊点内形成大块的初生β-Sn相,使得不同尺寸焊点内锡相和铋相的晶粒尺寸分布产生差异. Cu原子扩散速率的差异,Sn-58Bi焊点尺寸的减小有利于回流后界面金属化合物(IMC)的生长,并且在老化条件下,300 μm焊点界面IMC的生长速率为0.324 μm/day1/2,大于400 μm和760 μm焊点界面IMC的生长速率,300 μm焊点界面IMC需要更短的时间从扇贝状成长为平板状. 300 μm焊点中有更强的机械约束效应,导致300 μm焊点具有更高的抗剪切强度,回流后抗剪切强度达到了70.89 MPa,400 μm和760 μm焊点抗剪切强度分别为67.19 MPa和60.97 MPa.

     

    Abstract: The effect of reducing the size of reflow solder joints on the microstructure and morphology of Sn-58Bi solder joints was studied. The effect of reducing the size of solder joints at different aging times on the evolution of interfacial microstructure and shear properties of solder joints was also analyzed. The results showed that under the same cooling condition, the reduction of solder joint size resulted in a greater undercooling of solder joints during the solidification stage, the growth of β-Sn primary phases, and the differences in the grain size distribution of Sn and Bi phases within the solder joints. Due to the differences in the diffusion rates of Cu atoms, the reduction in the size of Sn-58Bi solder joint was beneficial to the growth of interfacial metallic compounds (IMCs) after reflowing. Meanwhile, under aging condition, the interfacial growth rate of IMC at the solder joint with size of 300 μm was greater than that with size of 400 μm and 760 μm. At the interface of solder joints, the joints with size of 300 μm needed a shorter time to grow from a scallop shape to a flatten shape. Due to constrain effect, the joint with size of 300 μm presented a higher shear strength compared with the joints with size of 400 μm and 760 μm.

     

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