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镁合金表面纳米TiSiN复合薄膜的制备及其结构和耐蚀耐磨性能分析

Preparation and characterization of structure and properties of nanoTiSiN films deposited on Mg alloys

  • 摘要: 为提高镁合金耐蚀和耐磨性,扩大其在航空领域的应用,采用反应磁控溅射法,分别在AZ31和Mg8Li两种镁合金基体上制备了复合TiSiN薄膜. 采用X射线荧光光谱、扫描电镜、原子力显微镜和X射线小角掠入射分别对薄膜表面元素分布、形貌、膜层结构和晶粒尺寸进行了分析. 采用电化学工作站和球盘式摩擦磨损试验机分别对薄膜在3.5%NaCl溶液中的腐蚀行为和在空气中的摩擦磨损性能进行了研究. 结果表明,薄膜中Ti和Si元素比例与靶材相近,元素在整个膜层表面呈高低交替的环形分布,Mg8Li基体上薄膜的分布较为均匀;薄膜主要由TiN和Ti2N两相组成,AZ31表面薄膜的晶粒尺寸和粗糙度均小于Mg8Li表面的薄膜;两种基体镀膜后的腐蚀电流密度降低了三个数量级,摩擦系数低于0.4,磨损率在10−6 m3/Nm数量级.

     

    Abstract: The work aims to improve corrosion and wear resistance of Mg alloys, TiSiN composite films were prepared on two groups Mg alloys by reactive magnetron sputtering in mixed Ar+N2 atmosphere by sputtering Ti-Si target. Chemical composition, surface morphology, crystalline structure and grain size were investigated by X-fluorescence (XRF), scanning electron microscopy (SEM), atomic force microscope (AFM) and grazing incidence X-ray diffraction (GIXRD), respectively. The corrosion behavior and wear resistance were studied by electrochemical workstation in 3.5% NaCl solution and ball-on-disc tribometer in air, respectively. Results show that the Ti, Si content of film is close to target material and present an alternating ring distribution on the whole coating surface, and Ti, Si elements in Mg8Li film are more evenly distributed. Crystal structure of films is mainly composed of Ti2N and TiN, the grain size and roughness of AZ31 film is lower than Mg8Li film. The corrosion current density of coatings decreased by three orders of magnitude, the friction coefficient is less than 0.4 and wear loss rate in an order of 10−6 m3·N−1m−1 magnitude. The films have good corrosion and wear resistance, the properties of thin film is affected by surface roughness and crystal size.

     

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