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TiN对Fe-Cr-C耐磨堆焊合金组织及耐磨性影响

Effect of TiN on microstructure and wear resistance of Fe-Cr-C hardfacing alloy

  • 摘要: 通过药芯焊丝的方式制备Fe-Cr-C-Ti-N和Fe-Cr-C堆焊层,讨论堆焊层中TiN对堆焊层耐磨性能和显微组织的影响. 利用洛氏硬度计检测堆焊层的宏观硬度,通过湿砂轮磨损试验机对堆焊层进行磨料磨损试验,利用X射线衍射仪(XRD)、扫描电镜(SEM)、能谱分析仪(EDS)、透射电子显微镜(TEM)等设备进行检测分析. 结果表明,含有TiN的堆焊层中,初生M7C3明显比不含TiN的组织细小,并且堆焊层硬度和耐磨性也相应提高. 通过热力学计算得出,熔池冷却过程中TiN先于M7C3析出. 由动力学计算可知TiN/M7C3的二维错配度为8.43%,TiN可做为初生M7C3的异质形核质点,使M7C3晶粒细化.

     

    Abstract: Fe-Cr-C-Ti-N and Fe-Cr-C Surfacing layers were prepared by flux cored wires. The effect of TiN on the wear resistance and microstructure of the surfacing layer was discussed. The rockwell hardness tester was used to test the macrohardness of the surfacing layer. The abrasive wear test of the surfacing layer is carried out by the wet grinding wheel wear tester. Using X ray diffractometer (XRD), scanning electron microscope (SEM), energy dispersive spectrometer (EDS), transmission electron microscopy (TEM) and other equipment for testing and analysis. The results showed that the primary M7C3 in the surfacing layer containing TiN was significantly smaller than that without TiN and the hardness and wear resistance of the surfacing layer were also improved. Through thermodynamic calculation, TiN is prior to precipitation of M7C3 in molten pool cooling process. According to the dynamics calculations, the two-dimensional misfit of TiN/M7C3 is 8.43%. TiN can be used as a heterogeneous nucleation site for primary M7C3, which refines the M7C3 grains.

     

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